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Record W4408779096 · doi:10.1029/2024gb008409

Water Column Structure and Nutrient Supply on the Northwest Atlantic Shelf: A Nitrate Isotope Study

2025· article· en· W4408779096 on OpenAlexafffund
Nadine Lehmann, Markus Kienast, Claire Normandeau, Peter Thamer, Brian A. Dempsey, Benoît Thibodeau, Carolyn Buchwald

Bibliographic record

VenueGlobal Biogeochemical Cycles · 2025
Typearticle
Languageen
FieldEnvironmental Science
TopicIsotope Analysis in Ecology
Canadian institutionsBedford Institute of OceanographyFisheries and Oceans CanadaDalhousie University
FundersOcean Frontier Institute
KeywordsWater columnNitrateOceanographyNutrientEnvironmental scienceIsotopeGeologyStable isotope ratioWater massChemistry

Abstract

fetched live from OpenAlex

Abstract The Northwest Atlantic continental shelf is a highly productive marine region with major uncertainties regarding the supply mechanisms of nutrients fueling productivity. This study uses nitrate isotopes (δ 15 N NO3 and δ 18 O NO3 ) from the Atlantic Zone Monitoring Program 2020 fall mission and an Optimum Multiparameter Analysis to evaluate on‐shelf nutrient transport versus biological supply pathways across three transects from the Laurentian Channel to the central Scotian Shelf. Surface waters showed an imprint of remineralized production, with partial nitrification creating an isotopically light (δ 15 N NO3 ≥2.7‰) surface lens extending from Cabot Strait across the coastal Scotian Shelf. A concurrent enrichment in δ 15 N NO3 and δ 18 O NO3 (<8.5‰, <7.4‰) alongside decreasing nitrate concentrations further indicated phytoplankton assimilation over the deep central shelf (overlying Emerald Basin), a process not observed across Cabot Strait or coastal shelf stations. Subsurface nutrients in Cabot Strait are highly regenerated (<43%), with increased bottom water δ 15 N NO3 signaling sedimentary denitrification in the deep Laurentian Channel. Conversely, subsurface nutrients on the Scotian Shelf were predominantly preformed (<86%), sustained by Cold Intermediate Water from the Gulf of St. Lawrence and warm North Atlantic Central Water (NACW) from offshore. Derived water mass contributions and a distinct isotopically light subsurface layer offshore (δ 15 N NO3 of >4.2‰)−characteristic of N 2 fixation in shallow NACW−indicate a stronger NACW imprint on the central Scotian Shelf compared to the Laurentian Channel and eastern shelf. Our results confirm the importance of slope water advection in supplying subsurface nutrients to the shelf while highlighting the seasonal imprint of recycled production on near‐shore surface waters during fall.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.084
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.217
Teacher spread0.212 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2025
Admission routes2
Has abstractyes

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