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Record W4408886805 · doi:10.1039/d5cc01110h

Metal-free alkene hydroboration with pinacolborane employing C<sub>6</sub>F<sub>5</sub>BH<sub>2</sub>·SMe<sub>2</sub> as a precatalyst

2025· article· en· W4408886805 on OpenAlex
Nikita A. Slesarchuk, George Doerksen, Petra Vasko, Timo Repo

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueChemical Communications · 2025
Typearticle
Languageen
FieldMedicine
TopicBoron Compounds in Chemistry
Canadian institutionsUniversity of Calgary
FundersHORIZON EUROPE Innovative EuropeHORIZON EUROPE Framework ProgrammeMitacsChina Scholarship CouncilAcademy of FinlandEuropean CommissionHelsingin Yliopisto
KeywordsHydroborationAlkeneChemistryMetalOrganic chemistryCombinatorial chemistryCatalysis

Abstract

fetched live from OpenAlex

C 6 F 5 BH 2 ·SMe 2 possesses a high catalytic activity for metal-free hydroboration by pinacolborane toward terminal and internal alkenes.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.002
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Research integrity
Consensus categoriesMeta-epidemiology (narrow)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.015
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.002
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0020.001
Bibliometrics0.0010.003
Science and technology studies0.0010.002
Scholarly communication0.0000.001
Open science0.0040.003
Research integrity0.0010.003
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.020
GPT teacher head0.286
Teacher spread0.265 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it