Halogen-substituted Li3InCl6: Insights into the Evolved Structure, Composition, and Ionic Conductivity
Bibliographic record
Abstract
Ternary Li-containing halides have gained significant interest for all-solid-state batteries because they show high Li-ion conductivity, and their structures can be modified. In this study, halogen substitution in Li3InCl6 was attempted to form Li3InCl6–xXx (X = F, Br, I) samples whose phase compositions and Li+ conductivity were characterized by X-ray diffraction and impedance spectroscopy. Based on the evolution of cell parameters, Cl can be substituted completely by F within the experimental limit of x ≤ 1.2, while by other halogens up to a solid solubility limit of x = 0.6 for Br, and x <0.1 for I. The Li-ion conductivity diminished with greater nominal compositions of X in the samples, especially as other phases exhibiting low conductivity are formed. These results suggest that increased polarizability of X is not a dominant factor influencing Li+ mobility in Li3InCl6–xXx.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".