Poly(α‐Aminophosphine Chalcogenide) Networks: Synthesis, Characterization, and Application for Metal Sequestration
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
ABSTRACT Quaternary mixtures of primary phosphine, chalcogen, diimine, and triimine were employed in polymerization reactions to give α‐aminophosphine chalcogenide polymer networks. Six networks were prepared that differed in the chalcogen (O, S) and the aryl substituents on the imine precursors (Ph, 4‐F‐C 6 H 4 , 2‐OH‐C 6 H 4 ). The swellability of the networks in different solvents was evaluated. Four networks displayed exceptional swelling (2–8 × mass increase) with polar aprotic solvents THF and DCM. A mono(α‐aminophosphine) oxide molecule was prepared as a molecular model of the parent network, and it was successfully coordinated to via monodentate binding through the oxide. The parent phosphine oxide network 6O effectively sequestered and Fe 3+ ions from THF solutions.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it