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Record W4409049098 · doi:10.1021/bk-2025-1501.ch002

Microwave-Assisted Depolymerization of Natural and Synthetic Polymers

2025· book-chapter· en· W4409049098 on OpenAlex
Md Al Mamunur Rashid, Kwang Ho Kim, Keunhong Jeong

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueACS symposium series · 2025
Typebook-chapter
Languageen
FieldChemistry
TopicMicrowave-Assisted Synthesis and Applications
Canadian institutionsUniversity of British Columbia
Fundersnot available
KeywordsDepolymerizationNatural (archaeology)Natural polymersPolymer sciencePolymerMaterials scienceBusinessPolymer chemistryComposite materialGeographyArchaeology

Abstract

fetched live from OpenAlex

Microwave-assisted depolymerization has emerged as a promising approach for recycling both natural and synthetic polymers. This chapter explores the fundamental principles, advantages, and applications of microwave heating in polymer degradation. Unlike conventional heating methods, microwave irradiation offers rapid, selective, and energy-efficient heating through direct interaction with materials. Key advantages include faster reaction rates, reduced side reactions, and improved product yields and selectivity. The dielectric properties of materials, penetration depth, and unique heating mechanisms are discussed. Applications to various polymers are reviewed, including PET, polycarbonate, polyurethanes, polyamides, and others. Case studies demonstrate significant reductions in reaction times and energy consumption compared to conventional heating methods. Microwave-assisted processes have shown particular promise for chemical recycling techniques like glycolysis, hydrolysis, and aminolysis. While challenges remain, such as the need for microwave-absorbing additives for some polymers, this technology offers a more sustainable and economically viable approach to polymer recycling. As global plastic waste continues to increase, microwave-assisted depolymerization presents an innovative solution to address environmental concerns and promote a circular economy for plastics.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Other · Consensus signal: none
Teacher disagreement score0.552
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.001
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.202
Teacher spread0.195 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it