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Record W4409149565 · doi:10.1002/cjce.25699

Efficient elevated temperature hydrogen direct purification and separation technology

2025· article· en· W4409149565 on OpenAlexvenueno aff
Peixuan Hao, Dongdong Wang, Fuhua Xu, Tongyu Liu, Lu Wang, Shuang Li, Yixiang Shi, Ningsheng Cai

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2025
Typearticle
Languageen
FieldMaterials Science
TopicHydrogen Storage and Materials
Canadian institutionsnot available
FundersTsinghua UniversityNational Natural Science Foundation of ChinaU.S. Department of Energy
KeywordsSeparation (statistics)HydrogenMaterials scienceChemistryChemical engineeringChromatographyProcess engineeringComputer scienceEngineeringMachine learningOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Hydrogen, essential as a clean energy carrier and chemical feedstock, demands purification processes that are both efficient and economical. This study presents an analysis of the elevated temperature hydrogen direct purification and separation (HDPS) technology, an innovative method for achieving high hydrogen recovery rates. The LaNi 4 Al alloy, utilized as an absorbent, operates effectively at elevated temperatures and exhibits resilience against impurities. The HDPS process is strategically designed, incorporating pressurization, absorption, co‐current blowdown at varied rates, and vacuum desorption, and is distinguished from conventional pressure swing adsorption (PSA) based on theoretical insights into their operational differences and similarities. Integrated with a methanol reforming module, a temperature swing adsorption (TSA) module, and a proton exchange membrane fuel cell (PEMFC), the pilot‐scale HDPS system outperforms traditional PSA methods in efficiency. The HDPS‐TSA process achieves excellent hydrogen recovery rates (91.28%) and purities (99.999%), satisfying the stringent requirements of fuel cells. The HDPS‐TSA system's electricity consumption and heat demand are comparable to or lower than those of traditional vacuum pressure swing adsorption (VPSA) and TSA processes, positioning it as a promising solution for sustainable hydrogen production systems.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score0.217

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.206
Teacher spread0.202 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2025
Admission routes1
Has abstractyes

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