Bibliographic record
Abstract
image [97‐74‐5] C 6 H 12 N 2 S 3 (MW 208.367) InChI = 1S/C6H12N2S3/c1‐7(2)5(9)11‐6(10)8(3)4/h1‐4H3 InChIKey = REQPQFUJGGOFQL‐UHFFFAOYSA‐N (reagent used as a sulfur transfer agent, source of monosulfide for carbon(sp 2 )‐sulfur bond formation or thioacylation) Alternative Names: monothiuram, tetramethyl thiuram monosulfide, tetramethylthiodicarbonic diamide, dimethylcarbamothioyl N , N ‐dimethylcarbamodithioate, TMTM. Physical Data: mp 106–110 °C, d 1.37 g cm −3 . Solubility: insoluble in H 2 O; soluble in most organic solvents such as EtOH, acetone, benzene, and diethyl ether. Form Supplied in: yellow powder, widely available. Preparative Methods: coupling from dithiocarbamic acid salt and dimethylcarbamothioic chloride. 1 Purification: can be purified by chromatography column, R f (50% ethyl acetate in hexane) 0.40. 1 Handling, Storage, and Precautions: the product is stable under standard ambient conditions. Present acute toxicity and aquatic hazard. Careful use due to odor. Forms explosive mixtures with air upon intense heating and decomposes to NO x , CO 2 , CO, or sulfur oxides. Incompatible with strong oxidizers. The reactivity and uses can be compared to thiram (also named tetramethylthiuram disulfide [137‐26‐8]).
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.003 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.001 | 0.000 |
| Insufficient payload (model declined to judge) | 0.009 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".