VUV Photolysis of silane with nitric oxide in solid neon
Why this work is in the frame
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Bibliographic record
Abstract
We report the results of vacuum-ultraviolet (VUV) photolysis of SiH4 and NO in solid neon at 3 K. Photolysis at 130 nm produced a complex range of products, including SiH2, Si2H6, and various silicon oxides. Additionally, with the support of quantum chemical calculations and D-isotopic substituted experiments, we tentatively identified a new species, H2SiN(H)O, as an intermediate in the reaction of SiH3 with NO. These findings provide new insights into the VUV photochemistry of SiH4 and NO in a solid matrix and offer valuable information for understanding silicon-based combustion chemistry and astrochemistry.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it