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Record W4409291564 · doi:10.1016/j.fochx.2025.102451

Fatty acids and fatty alcohol esters as novel markers of authenticity and extraction method of commercial avocado oil

2025· article· en· W4409291564 on OpenAlexaff
Luis Martín Marín‐Obispo, Arturo A. Mayorga-Martínez, Diana Jessica Obispo‐Fortunato, Jorge Abraham Clorio‐Carrillo, Claudia Gonzalez Viejo, Sigfredo Fuentes, Timothy Schwinghamer, Verónica Patiño-González, Carmen Hernández‐Brenes

Bibliographic record

VenueFood Chemistry X · 2025
Typearticle
Languageen
FieldAgricultural and Biological Sciences
TopicPlant Physiology and Cultivation Studies
Canadian institutionsAgriculture and Agri-Food Canada
FundersInstituto Tecnológico y de Estudios Superiores de Monterrey
KeywordsAlcoholExtraction (chemistry)ChemistryFood scienceFatty alcoholChromatographyOrganic chemistry

Abstract

fetched live from OpenAlex

The lack of regulations on avocado oil authenticity enabled producers to blend it with cheaper oils without declaring it on the label. This study explored fatty acids (FA) and fatty alcohol esters (FAE) as innovative markers of avocado oil purity and extraction method. Only 40 % of the samples met the FA standards. Regarding FAE, extra virgin samples showed a maximum concentration of 2674.12 ± 570.98 mg total FAE·kg −1 oil, significantly higher than the 640.98 ± 220.06 mg total FAE·kg −1 oil observed in refined samples, making FAE novel markers of extraction method. Furthermore, a canonical discriminant analysis using Wilk's statistic (Λ = 0.008, F 126, 1028.2 = 8.87, p < 0.0001), based on fault concentrations (high, medium, low) of the allegedly pure samples, revealed that the high- and medium-fault clusters aligned closely with declared blends containing canola or safflower oils . FA and FAE are promising molecules to detect adulteration in avocado oil.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.005

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0010.001
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.028
GPT teacher head0.283
Teacher spread0.255 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2025
Admission routes1
Has abstractyes

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