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Record W4409374868 · doi:10.1029/2024gc012038

Redox‐State and Bioproductivity of the Glaciogenic Early Cryogenian Rapitan Iron Formation (Cranswick River, Canada): Constraints From Combined Cadmium—Chromium Isotopes

2025· article· en· W4409374868 on OpenAlexaffabout
Robert Frei, Geoff Baldwin, Michael G. Babechuk, Balz S. Kamber, Elizabeth C. Turner

Bibliographic record

VenueGeochemistry Geophysics Geosystems · 2025
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicGeochemistry and Elemental Analysis
Canadian institutionsMemorial University of NewfoundlandLaurentian University
Fundersnot available
KeywordsCadmiumChromiumGeologyRedoxOxidation stateIsotopeGeochemistryEarth scienceChemistryMetalInorganic chemistry

Abstract

fetched live from OpenAlex

Abstract The Rapitan Group (Northwest Territories, Canada) includes banded iron formation (BIF), an unusual sediment type that is associated with late Neoproterozoic glaciations, in this case, the early Cryogenian Sturtian glaciation. New non‐traditional stable isotope data from jasper and hematite iron formation (IF) from the Cranswick River area contribute new insights regarding water chemistry changes in the respective depositional basin during glacier advance and retreat. Cr isotope signatures are characterized by strongly positively fractionated δ 53 Cr values (+0.68–1.47‰), attesting to strongly oxidized surface waters during the entire depositional episode. Relatively weakly fractionated δ 114 Cd isotope signatures (−0.02 to +0.28‰), and the absence of organic matter in the samples, indicate a low bioproductivity during BIF deposition. Detailed fluctuations over an intermittent glacier advance and retreat cycle recorded in the studied section, however, reveal an ephemeral increase in primary production (excursion to slightly elevated δ 114 Cd values) just after deposition of a diamictite layer, which agrees with corresponding elevated δ 53 Cr values. This evidence attests to the sensitivity of the Cd‐Cr double isotope tracer applied to BIFs to reconstruct changes in the surface waters of depositional basins and track climate changes that accompanied the glacial episodes. When compared to data from the younger (Marinoan/Ediacaran) Urucum BIF in Brazil, the Rapitan section differs by lack of negative Ce anomalies in its rare earth element patterns, implying that water column oxidation was not as strong during the early Cryogenian as compared to the Marinoan/Ediacaran glacial episodes.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.278
Threshold uncertainty score0.954

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.003
GPT teacher head0.156
Teacher spread0.153 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2025
Admission routes2
Has abstractyes

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