Synthesis of High Solids Alkyds Modified with Reactive Diluents for Encapsulation and Use in Self-healing Coatings
Bibliographic record
Abstract
A great effort has been devoted to the research of self-healing coatings, as they provide anticorrosive protection even when the painting is damaged [1]. The encapsulation of drying oils is an established strategy to promote self-healing. Microcapsules release the seed oil upon mechanical damage, which triggers self-healing in the coating defect as the oil undergoes oxidative polymerization [2]. Alkyds are also a great candidate for microencapsulation due to their green nature, oxidative-driven polymerization, and better anticorrosive properties than seed oils [3]. However, the high viscosity of alkyds imposes great challenges for their encapsulation. In this work, a high solids alkyd from dehydrated castor oil (DCO) was developed with suitable viscosity for microencapsulation using seed oil-based reactive diluents.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".