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Record W4409537993 · doi:10.1002/cssc.202500203

Transient Absorption Microscopy Explores the Effect of Pt Deposition on Charge Carrier Dynamics in Individual Carbon Nitride Particles

2025· article· en· W4409537993 on OpenAlexafffund
Sutripto Khasnabis, Cassandra Mesburis, Robert Godin

Bibliographic record

VenueChemSusChem · 2025
Typearticle
Languageen
FieldMaterials Science
TopicElectronic and Structural Properties of Oxides
Canadian institutionsOkanagan University CollegeUniversity of British Columbia, Okanagan CampusUniversity of British Columbia
FundersNatural Sciences and Engineering Research Council of CanadaCanada Foundation for Innovation
KeywordsMicrosecondTrappingDeposition (geology)Chemical physicsAbsorption (acoustics)Charge carrierUltrafast laser spectroscopyMaterials scienceCarbon nitrideCarbon fibersCharge (physics)PopulationChemistryAnalytical Chemistry (journal)NanotechnologyOptoelectronicsPhotocatalysisOpticsLaserPhysicsCatalysisEnvironmental chemistry

Abstract

fetched live from OpenAlex

) photocatalysts, using a homebuilt microsecond diffuse reflectance transient absorption microscopy setup. It is found that Pt deposition lengthens the overall charge half-lives about threefold, while having a spatial preference for binding with respect to defects that induce charge trapping in the μs-s timescale. The initial trapped charge population shows a slight decrease after Pt deposition, suggesting that the more reactive and mobile charges are extracted by Pt sites, leaving behind deeply trapped and long-lived charges. The results emphasize that spatial heterogeneity of surface cocatalysts likely plays a major role in controlling the charge carrier dynamics and activity of photocatalysts.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.370

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.246
Teacher spread0.236 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2025
Admission routes2
Has abstractyes

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