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Record W4409632341 · doi:10.1016/j.ejrh.2025.102379

Insights into groundwater hydrochemistry and origin of the hydrocarbon contaminated karst aquifers, SW Iran

2025· article· en· W4409632341 on OpenAlexaff
Farshad Alijani, Narges Bayat, Hamid Reza Nassery, Gesine D. Lorenz, Florian Heine, Matthew I. Leybourne

Bibliographic record

VenueJournal of Hydrology Regional Studies · 2025
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicGroundwater and Isotope Geochemistry
Canadian institutionsGeological Survey of Canada
Fundersnot available
KeywordsKarstAquiferGroundwaterGeologyContaminationHydrology (agriculture)GeochemistryEnvironmental sciencePaleontologyEcologyGeotechnical engineering

Abstract

fetched live from OpenAlex

Khuzestan, Ilam, Lorestan, and Chaharmahal and Bakhtiari provinces in southwest of Iran. In this study, conventional geochemical, stable isotopes of H 2 O (δ 2 H, δ 18 O), SO 4 (δ 34 S, δ 18 O), and dissolved inorganic carbon (δ 13 C DIC ) were employed on the samples collected in February 2021, August 2021, and February 2022 from SW Iran. By the use of hydrogeochemical diagrams, sulfuric samples (SS), non-sulfuric samples (NSS), and oil field water (OFW) samples in karst aquifers have been distinguished. The findings reveal that: (1) the major chemical composition of the SS, NSS, and OFW samples consist of CaSO 4 , CaHCO 3 , and NaCl types, respectively; (2) the δ 2 H H2O values range between −17.37 and −15.86 ‰ V-SMOW and the δ 18 O H2O values range between −4.49 and −4.18 ‰ V-SMOW for the SS and NSS, indicating that they originated from local rainwater; (3) the δ 34 S SO4 and δ 18 O SO4 values of dissolved sulfate of SS, NSS, and OFW indicate that the sulfate resulted from interactions between water and rocks, particularly evaporitic rocks such as gypsum and anhydrite; and (4) the δ 13 C DIC values vary extensively, ranging from −16 ‰ to + 7 ‰ V-PDB. Higher δ 13 C DIC signatures are consistent with biogeochemical processes (i.e., methanogenesis) or exchange with marine carbonates. (5) The concentration of total petroleum hydrocarbons (TPH) ranged from 26.3 to 19,670 μg/L in the groundwater samples.Toluene was the most abundant species of BTEX in all samples. • The concentration of total petroleum hydrocarbons (TPH) ranged from 26.3 to 19,670 μg/L in the groundwater samples. • Hydrogeochemistry and multiple isotopes uses to study karst waters in SW Iran. • Hydrochemical characteristics of karst groundwaters are different. • Halite and gypsum dissolution are the main salinization processes. • Methanogenesis is supported by the δ 13 C DIC in NSS.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.145
Threshold uncertainty score0.398

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.018
GPT teacher head0.242
Teacher spread0.224 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations5
Published2025
Admission routes1
Has abstractyes

Explore more

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