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Record W4410121113 · doi:10.5382/econgeo.5151

The Origin and Enrichment of Sedimentary Basin Lithium Brines: A Case Study From the Upper Devonian Leduc Formation, Alberta Basin, Canada

2025· article· en· W4410121113 on OpenAlexaboutno aff
Kristina L. Butler, LeeAnn Munk, David F. Boutt, Natasha Morris, Jeffrey R. Kennedy, Puspendu Saha, Madigan Blake, Manuel Justin Custado, Daniel Ibarra

Bibliographic record

VenueEconomic Geology · 2025
Typearticle
Languageen
FieldEngineering
TopicHydrocarbon exploration and reservoir analysis
Canadian institutionsnot available
FundersBrown University
KeywordsGeologyDevonianStructural basinSedimentary rockGeochemistrySedimentary basinPaleontology

Abstract

fetched live from OpenAlex

Abstract Direct extraction of lithium from oil field brines, herein referred to as “sedimentary basin lithium brines,” is emerging as an economical and environmentally responsible alternative to hard-rock and salar-style brine resources. Relative to the major lithium chemical-producing countries, North America has scarce traditional lithium ore deposits. Sedimentary basin lithium brines present a promising and readily available domestic supply of lithium. Elevated lithium concentrations (>50 mg/L) are known in hydrocarbon fields across North America, but the origin of these brines, the lithium sources, and lithium enrichment mechanisms are largely debated or unknown. Using the Upper Devonian Leduc Formation (Alberta basin, Canada) as a case study, we document the complexity of unraveling brine genesis and evolution. Competing hypotheses regarding Leduc brine origin, postformational brine modification, and lithium sources confound an understanding of the lithium resource homogeneity and longevity. Using brine-dissolved species and isotopic data, we show that the Leduc brines are regionally geochemically distinct across the Devonian Leduc Formation reef complexes. We conclude that these brines originate from both evaporatively concentrated seawater and the dissolution of evaporite sequences and were subsequently modified by local mixing, diagenesis, and rock-water interaction processes. This compositional heterogeneity has implications for lithium resource exploration, production, and valuation of the Leduc Formation and other sedimentary basin lithium brine resources.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.724
Threshold uncertainty score0.284

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.206
Teacher spread0.200 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations12
Published2025
Admission routes1
Has abstractyes

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