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Record W4410212542 · doi:10.1021/acssuschemeng.4c09559

Production of Bioderived Graphitizable Materials by Alternative Catalytic Processing: Technoeconomic Assessment and Upscaling Insights

2025· article· en· W4410212542 on OpenAlexaff
Mehdi Mennani, Anass Ait Benhamou, Huixin Xiu, Christina Scheu, Zineb Kassab

Bibliographic record

VenueACS Sustainable Chemistry & Engineering · 2025
Typearticle
Languageen
FieldMaterials Science
Topicbiodegradable polymer synthesis and properties
Canadian institutionsUniversité Laval
Fundersnot available
KeywordsProduction (economics)CatalysisBiochemical engineeringWaste managementEnvironmental scienceProcess engineeringComputer scienceEngineeringChemistryEconomicsOrganic chemistry

Abstract

fetched live from OpenAlex

In this work, we examine the production of bioderived graphitizable materials through a catalytic graphitization approach utilizing biomass precursors. The objective is to establish a sustainable and economically feasible process that matches conventional methodologies, including the Acheson process, natural graphite extraction, and electrochemical approaches. The research integrates experimental evaluations with techno-economic analyses to juxtapose the uncatalyzed and catalyzed methodologies, examine the scalability from laboratory to industrial production, and assess the overall environmental impact. The findings demonstrate that the catalytic process markedly enhances the yield by up to 30%, diminishes energy consumption, and exhibits desirable cost efficiency. Furthermore, the graphitic carbon generated possesses a degree of graphitization approximating 0.81, along with a d -spacing of 0.33869 nm of the graphitic planes. A comprehensive characterization of biographite (BG) revealed the successful development of high-quality graphitic domains. The catalytic process facilitates relatively rapid graphitization accompanied by a significant reduction in total energy requirements. Noteworthy that although issues pertaining to yield consistency and scalability persist, the study concludes that with further optimization of the process and pilot-scale experimentation, biomass catalytic graphitization possesses considerable potential to meet the increasing demand for sustainable graphite materials in sectors such as energy storage and electronics.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.005

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.000
Science and technology studies0.0000.000
Scholarly communication0.0010.001
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.209
Teacher spread0.204 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations6
Published2025
Admission routes1
Has abstractyes

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Same venueACS Sustainable Chemistry & EngineeringSame topicbiodegradable polymer synthesis and propertiesFrench-language works237,207