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Record W4410217998 · doi:10.1016/j.aca.2025.344167

Locally-weighted-RoBoost-PLS: a multivariate calibration approach to simultaneously cope with non-linearities and outliers

2025· article· en· W4410217998 on OpenAlexaff
Daniele Tanzilli, Lorenzo Strani, Maxime Metz, Jean Michel Roger, Matthieu Lesnoff, Cyril Ruckebusch, Marina Cocchi, Raffaele Vitale

Bibliographic record

VenueAnalytica Chimica Acta · 2025
Typearticle
Languageen
FieldChemistry
TopicSpectroscopy and Chemometric Analyses
Canadian institutionsEncana (Canada)
Fundersnot available
KeywordsChemistryOutlierMultivariate statisticsCalibrationMultivariate analysisStatisticsPattern recognition (psychology)Artificial intelligenceMathematicsComputer science

Abstract

fetched live from OpenAlex

BACKGROUND: Partial Least Squares regression (PLS) is a widely used tool for predictive modelling, particularly when dealing with multivariate datasets with dependent variables exhibiting strong collinearities. However, when relationships between variables are non-linear or atypical data points have to be coped with, PLS calibration models may face challenges. In recent years, different variants of the original PLS algorithm have been proposed to overcome these limitations. On the one hand, several robust regression methods that down-weigh outlying observations during the model training phase like RoBoost-PLS have been developed to reduce the detrimental effect of outliers on the performance of PLS. On the other hand, local modelling approaches, like K-Nearest-Neighbours-Locally-Weighted-PLS (KNN-LW-PLS), have been designed to handle non-linearities by fitting for each new incoming sample a separate linear calibration model considering only its nearest-neighbours. Unfortunately, none of these strategies can address the two aforementioned problems simultaneously. This paper introduces a novel approach named Locally-Weighted-RoBoost-PLS (LW-RoBoost-PLS), that combines the strengths of both local and robust modelling methodologies in order to deal with non-linearities while mitigating at the same time the influence of outliers. RESULTS: The performance of LW-RoBoost-PLS was evaluated on simulated and real industrial data (with this latter resulting from a continuous Acrylonitrile-Butadiene-Styrene ABS production process conducted at Versalis S.p.A.), both characterised by the simultaneous presence of outliers and non-linear relationships among measured variables. In the two case-studies investigated here, LW-RoBoost-PLS outperformed RoBoost-PLS and KNN-LW-PLS, achieving considerable reductions in the prediction error and prediction bias, which demonstrates that this technique permits to effectively overcome the limitations of the other approaches. SIGNIFICANCE: This paper describes a novel multivariate calibration approach named LW-RoBoost-PLS, which provides a solution for predictive modelling in scenarios where outliers and non-linearities co-exist. LW-RoBoost-PLS simultaneously handles non-linearities and outliers by combining local and robust modelling strategies, leading to improved prediction accuracy and reduced bias.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.743
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.254
Teacher spread0.244 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations9
Published2025
Admission routes1
Has abstractyes

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