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Record W4410789503 · doi:10.1080/03067319.2025.2510428

Functionalised hydroxyapatites for heavy metals removal from water: a review

2025· review· en· W4410789503 on OpenAlexaff
Sara Fatine, A. Laghzizil, Jean‐Michel Nunzi

Bibliographic record

VenueInternational Journal of Environmental & Analytical Chemistry · 2025
Typereview
Languageen
FieldEnvironmental Science
TopicAdsorption and biosorption for pollutant removal
Canadian institutionsQueen's University
Fundersnot available
KeywordsHydroxyapatitesHeavy metalsEnvironmental chemistryEnvironmental scienceChemistryGeochemistryGeologyMaterials scienceMetallurgyCalcium

Abstract

fetched live from OpenAlex

The emergence of pollutants in the aquatic environment and their impact on living species is alarming and a source of growing concern. Among these concerns, the removal of heavy metal ions from wastewater is a major challenge for the protection of the environment and for human health. Since standard primary and secondary treatment plants fail to eliminate these harmful species, a cost-effective tertiary treatment approach is proposed. The most commonly used methods for heavy metal removal are adsorption, precipitation, membrane, electric and osmosis. According to recent studies, it has been shown that adsorption is the most adopted technique using porous and surface functionalised adsorbents. With the advancement of technology and the requirement of environmental protection, many adsorbents have been used for wastewater treatment, based on to their effectiveness. Hydroxyapatite-based functional materials have attracted significant attention as green and environmentally friendly adsorbents due to their outstanding ability to remove various inorganic and organic pollutants from wastewater. Their open structure and porous surface support suitable adsorption mechanisms including precipitation, ion exchange, surface complexation, and neutralisation reactions. Developing HAp functionalised with various chelating agents has been proven to achieve a synergistic effect to improve the removal of heavy metals from wastewater. This topic has attracted the attention of the scientific community due to the good efficiency of hydroxyapatite-based materials and their ease of preparation as well as their low cost. This review critically examines recently publications on this topic.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Review · Consensus signal: Review
Teacher disagreement score0.944
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.002
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0270.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.018
GPT teacher head0.303
Teacher spread0.285 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designNot applicable
Domainnot available
GenreReview

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2025
Admission routes1
Has abstractyes

Explore more

Same venueInternational Journal of Environmental & Analytical ChemistrySame topicAdsorption and biosorption for pollutant removalFrench-language works237,207