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Record W4411531409 · doi:10.1021/acschembio.5c00178

Feature-Based Molecular Networking Guided Characterization of Clonocoprogen Siderophores with Anti-<i>Pseudomonas aeruginosa</i> Activity in Nematodes through Immune Up-Regulating Effects

2025· article· en· W4411531409 on OpenAlexaff
Guoliang Zhu, Weize Yuan, Kun Wang, Huimin Wu, Kangjie Lv, Xinye Wang, Alex Tuffour, Biao Ren, Jingyu Zhang, Cheng‐Lin Jiang, Yi Jiang, Tom Hsiang, Pengfei Yu, Frederick M. Ausubel, Lixin Zhang, Huanqin Dai, Xueting Liu

Bibliographic record

VenueACS Chemical Biology · 2025
Typearticle
Languageen
FieldPharmacology, Toxicology and Pharmaceutics
TopicPiperaceae Chemical and Biological Studies
Canadian institutionsUniversity of Guelph
FundersNational Key Research and Development Program of ChinaHigher Education Discipline Innovation ProjectState Key Laboratory of Bioreactor EngineeringScience and Technology Commission of Shanghai MunicipalityNational Natural Science Foundation of China
KeywordsPseudomonas aeruginosaSiderophoreBiologyAntibioticsMicrobiologyImmune systemPyoverdineBacteriaAntibiotic resistanceCaenorhabditis elegansImmunityGeneImmunologyGenetics

Abstract

fetched live from OpenAlex

Antibiotic resistance poses a severe threat to human health, necessitating research into antibiotics with unique mechanisms to combat drug resistance. Natural siderophores and their synthetic derivatives have become a promising resource for the development of anti-infectious agents. In this study, we introduce a new anti-infective agent with a mode of action that enhances host immunity without exerting direct antibacterial activity. We identified immune-activating clonocoprogen siderophores from the fungus Clonostachys rosea isolate CR15020 using an integrated approach, including genome mining, feature-based molecular networking (FBMN) and a nematode screening model. Although these siderophores displayed no inherent antibacterial properties, they significantly improved survival of Caenorhabditis elegans exposed to Pseudomonas aeruginosa, with EC 50 values ranging from 1.85 to 10.86 μM. This protection was achieved through up-regulation of the nematode’s p38-MAPK and DAF/IGF immune pathways, as well as reducing the excretion of pyoverdine by P. aeruginosa . By leveraging immune modulation rather than direct bacterial inhibition, this approach offers a promising alternative to conventional antibiotics, addressing the urgent challenge of antibiotic resistance.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.075
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.043
GPT teacher head0.369
Teacher spread0.326 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes1
Has abstractyes

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