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Record W4412055777 · doi:10.1029/2025jd043394

Estimating Urban CH4 ${\text{CH}}_{4}$ Emissions From Satellite‐Derived Enhancement Ratios of CH4 ${\text{CH}}_{4}$, CO2 ${\text{CO}}_{2}$, and CO

2025· article· en· W4412055777 on OpenAlexafffund
Jon‐Paul Mastrogiacomo, M. Crippa, Cameron G. MacDonald, Coleen M. Roehl, Debra Wunch

Bibliographic record

VenueJournal of Geophysical Research Atmospheres · 2025
Typearticle
Languageen
FieldEnvironmental Science
TopicAtmospheric and Environmental Gas Dynamics
Canadian institutionsUniversity of Toronto
FundersCanadian Space AgencyUniversität Bremen
KeywordsObservatoryEnvironmental scienceSatelliteMethaneAtmospheric sciencesGreenhouse gasCarbon monoxideCarbon fibersCarbon dioxideTroposphereEmission inventoryMeteorologyClimatologyGeographyChemistryAir quality indexPhysicsMathematicsGeologyAstrophysics

Abstract

fetched live from OpenAlex

Abstract Urban centers are an important source of anthropogenic methane emissions and the focus of recent policy efforts aimed at emission reductions. But, emissions from urban areas are poorly characterized except in the few cities with robust measurement infrastructure. Satellite measurements offer a means for monitoring urban emissions. We use colocated measurements of methane () and carbon monoxide (CO) from the TROPOspheric Monitoring Instrument (TROPOMI) and carbon dioxide () from the Orbiting Carbon Observatory 2 and Orbiting Carbon Observatory 3 (OCO‐2/3) to calculate :, :CO, and CO: enhancement ratios over 103 cities. We compare our enhancement ratios to those derived from ground‐based instruments in Los Angeles and find good agreement. Then, we combine our enhancement ratios with CO and inventories to calculate emissions and find good agreement with estimates from past studies. Finally, we compare our satellite‐based enhancement ratios to those computed from the bottom‐up globally gridded emission inventories, and we find significant differences between them. Combining results from the three enhancement ratios, we find EDGARv8 to best represent emissions in urban areas with mean errors of 34% compared to CAMS‐GLOB‐ANTv6.2 (based on EDGARv6.1), and CEDSv2021 with mean errors of 43% and 49%, respectively. These differences are largely driven by EDGARv8 changes in South‐Central and East Asia. We also find that EDGARv8 and HTAPv3 underestimate CO emissions by a factor of 2–5 for cities in Iran, Turkmenistan, and Argentina. Finally, we find that CO emissions are overestimated in some cities in Europe by a factor of 2.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.048
Threshold uncertainty score0.096

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.308
Teacher spread0.292 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2025
Admission routes2
Has abstractyes

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