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Record W4412385480 · doi:10.1180/mgm.2025.31

Gorbunovite CsLi<sub>2</sub>(Ti,Fe<sup>+3</sup>)(Si<sub>4</sub>O<sub>10</sub>)(F,OH,O)<sub>2</sub> – a new mica supergroup mineral from the Darai-Pioz alkaline massif, Tajikistan

2025· article· en· W4412385480 on OpenAlexaff
Atali A. Agakhanov, Leonid A. Pautov, Igor Pekov, Vladimir Yu. Karpenko, Oleg I. Siidra, Elena Sokolova, F. C. Hawthorne, Vyacheslav A. Muftakhov, Anatoly V. Kasatkin

Bibliographic record

VenueMineralogical Magazine · 2025
Typearticle
Languageen
FieldMaterials Science
TopicCrystal Structures and Properties
Canadian institutionsUniversity of Manitoba
FundersRussian Science Foundation
KeywordsSupergroupMassifMicaMineralMineralogyGeologyGeochemistryCrystallographyChemistryMaterials scienceMetallurgyPaleontology

Abstract

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Abstract Gorbunovite, CsLi 2 (Ti,Fe +3 )(Si 4 O 10 )(F,OH,O) 2 , a new caesium trioctahedral mica, was discovered in the Darai-Pioz alkaline massif, Tajikistan. The mineral is named after the Russian chemist, leader of the Tajik-Pamir Expedition, Academician Nikolai Petrovich Gorbunov (1892–1938). Gorbunovite occurs as lamellar grains or flakes from 2 μm to 0.2 mm in a quartz–pectolite aggregate and is associated with quartz, fluorite, pectolite, baratovite, aegirine, leucosphenite, neptunite, reedmergnerite, orlovite, sokolovaite, mendeleevite-(Ce), odigitriaite, pekovite, zeravshanite, kirchhoffite and garmite. The mineral is colourless, transparent, with vitreous lustre. Mohs hardness is 2½. D meas. is 3.28 (2), D calc is 3.302 g/cm 3 . Gorbunovite is optically biaxial (–), α = 1.609(2), β = 1.621(2), γ = 1.623(2), 2V meas. 30(5) and 2V calc. 44. Gorbunovite is monoclinic, space group C 2/ m, C 2 or Cm (polytype 1 M ), a = 5.236(2), b = 9.054(4), c = 10.767(4) Å, β = 99.61(4)°, V = 503.3(6) Å 3 and Z = 2. The strongest lines in the powder X-ray diffraction pattern [ d , Å, ( I )] are: 4.49 (25), 3.94 (20), 3.69 (46), 3.57 (23), 3.45(34), 2.991 (42), 2.608 (77), 2.581 (100), 2.240 (33), 2.188 (62), 2.020 (24), 1.722 (27) and 1.511 (23). Chemical composition (microprobe analysis; H 2 O, Li 2 O – SIMS) is: SiO 2 47.44, TiO 2 9.40, Al 2 O 3 0.66, MgO 0.63, Fe 2 O 3 3.64, ZnO 1.01, K 2 O 0.39, Cs 2 O 26.64, Li 2 O 5.83, H 2 O 0.89, F 4.48, –O=F 1.89, total 99.17. The empirical formula is (Cs 0.96 K 0.04 ) Σ1.00 Li 1.98 (Ti 0.60 Fe +3 0.23 Mg 0.08 Al 0.07 Zn 0.06 ) Σ1.04 Si 4.00 O 10 (F 1.19 OH 0.50 O 0.31 ) Σ2 .

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Science and technology studies, Scholarly communication, Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.033
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0030.002
Meta-epidemiology (broad)0.0030.001
Bibliometrics0.0010.002
Science and technology studies0.0010.002
Scholarly communication0.0020.001
Open science0.0030.002
Research integrity0.0010.002
Insufficient payload (model declined to judge)0.0010.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.223
Teacher spread0.209 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes1
Has abstractyes

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