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Record W4412551228 · doi:10.1002/adfm.202506583

Reversible Photochromism and Multicolor Luminescence Modulation for X‐Ray Detection and Secure Information Encryption

2025· article· en· W4412551228 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueAdvanced Functional Materials · 2025
Typearticle
Languageen
FieldEngineering
TopicAdvanced Semiconductor Detectors and Materials
Canadian institutionsConcordia University
FundersNational Health and Medical Research CouncilNational Natural Science Foundation of China
KeywordsPhotochromismMaterials scienceLuminescenceEncryptionModulation (music)X-rayOptoelectronicsOpticsNanotechnologyComputer sciencePhysicsComputer security

Abstract

fetched live from OpenAlex

Abstract Conventional X‐ray‐responsive materials face significant limitations including instability, complex processing, low resolution, or single‐mode signaling, which hinder advanced X‐ray detection, imaging, and anti‐counteferting. Addressing these challenges, a comprehensive investigation is conducted on multifunctional Eu 3+ ‐doped Gd 2 SiO 5 , a material that combines photochromism with radioluminescence and photoluminescence. Through experimental and theoretical analyses, the reversible X‐ray‐induced photochromism (arising from oxygen vacancy‐related color centers) and tunable multicolor emission (from self‐trapped exciton states and Eu 3+ transitions) are revealed. These mechanisms enable dual‐mode, linear optical responses to X‐ray dose via dynamic absorption and emission modulation. The optimized phosphor achieves high light yield (47041 photons MeV −1 ), high spatial resolution, and stability under harsh conditions. Integration into flexible PDMS films facilitates high‐resolution X‐ray imaging devices. Critically, by leveraging intrinsic multicolor luminescence, a prototype of selective information encryption using optical filters and decryption via RGB color channel separation is demonstrated. These findings highlight the versatility of Gd 2 SiO 5 :Eu 3+ phosphors and their potential to drive innovations in next‐generation X‐ray imaging, sensing, and security technologies.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.127
Threshold uncertainty score0.632

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.006
GPT teacher head0.207
Teacher spread0.201 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it