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Record W4412724749 · doi:10.1021/acs.langmuir.5c01848

Organic–Inorganic Hybrid Materials for Trace Detection of Formaldehyde at Room Temperature

2025· article· en· W4412724749 on OpenAlexafffund
Shahrzad Ghodrati, Bhoomi Het Mavani, Keong Jung Kim, Katherine M. E. Stewart, Alexander Penlidis

Bibliographic record

VenueLangmuir · 2025
Typearticle
Languageen
FieldEngineering
TopicAdvanced Chemical Sensor Technologies
Canadian institutionsTrent UniversityUniversity of Waterloo
FundersNatural Sciences and Engineering Research Council of CanadaCanada Research ChairsGovernment of Canada
KeywordsDopantPolyanilineMaterials scienceFormaldehydePolymerChemical engineeringOxideFourier transform infrared spectroscopyHybrid materialConductive polymerMetalDopingNanotechnologyChemistryComposite materialOrganic chemistryMetallurgyPolymerization

Abstract

fetched live from OpenAlex

Detection and monitoring of trace gas analytes have become essential with the rapid advancements in manufacturing technology. Despite progress in developing gas sensing materials, many still struggle to meet fundamental requirements such as adequate sensitivity and stability, particularly due to high operational temperatures. To address this limitation, this study evaluates polymer–metal oxide hybrid materials designed for trace gas detection at room temperature. Polyaniline (PANI) hybrids doped with 5 wt % of TiO 2, SnO 2, ZnO, and Co 3 O 4 were synthesized in situ and characterized using FTIR, SEM, TEM, and EDX to analyze their chemical structure, morphology, and dopant incorporation. Pristine PANI and its metal oxide-doped variants were exposed to formaldehyde, and their sensing performance was evaluated at room temperature. Among the tested materials, PANI with 5 wt % Co 3 O 4 exhibited relatively higher sensitivity toward formaldehyde, attributed to the modified morphology and enhanced interactions as a result of Co 3 O 4 incorporation in PANI. To further investigate the effect of dopant concentration, PANI composites with lower Co 3 O 4 loadings were also evaluated. These findings provide insight into optimizing polymer-based gas sensors for enhanced performance at ambient conditions.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.007
Threshold uncertainty score0.414

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.003
GPT teacher head0.195
Teacher spread0.191 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2025
Admission routes2
Has abstractyes

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