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Record W4412816023 · doi:10.18280/ijdne.200603

Enhanced Cu (II) Removal by Iron-Graphite Electrocoagulation: Kinetics, Efficiency and Hydrogen Co-Production

2025· article· en· W4412816023 on OpenAlexvenueno aff
Amjed Sabah Kamil Janabi, Hayder M. Abdul‐Hameed

Bibliographic record

VenueInternational Journal of Design & Nature and Ecodynamics · 2025
Typearticle
Languageen
FieldEngineering
TopicEnvironmental remediation with nanomaterials
Canadian institutionsnot available
FundersUniversity of Baghdad
KeywordsElectrocoagulationKineticsHydrogen productionGraphiteHydrogenProduction (economics)MetallurgyChemical engineeringMaterials scienceChemistryNuclear chemistryEngineeringPhysicsOrganic chemistryPhysical chemistry

Abstract

fetched live from OpenAlex

Electrocoagulation (EC) process is an effective electrochemical method of heavy metal removal in wastewater.The removal of Cu (II) in aqueous solutions using Fe-Gr electrodes was studied in the present study in both batch and continuous modes.This was to determine the efficiency of removal of Cu (II) under different operating conditions, such as current density, pH, and treatment time.The originality of the work is that it uses Fe-Gr electrodes, which have the coagulant effect of iron and the high adsorption capacity of graphite.The electrode performance is better, and the removal efficiency is higher for Cu (II) and hydrogen production.The specific surface area (BET) of graphite electrode is 2.6 (m 2 /g).The experimental results showed that the pseudo-second-order model was the best fit to the Cu (II) removal kinetics, where R 2 = 0.98, which was higher than that of the first-order model, R 2 = 0.86, indicating a strong correlation.Graphite offers high electrical conductivity and chemical stability, which facilitates faster electron movement and improved electrode kinetics.During batch experiments, an applied voltage of 50 V and an inter-electrode distance of 3 cm led to almost total removal of Cu (II) in 25 minutes.A 90% percent removal efficiency with H2 produced was attained with continuous EC experiments at a flow rate of 0.3 L/min and the weight of sludge 12 g.H2 gas generation (0.152, 0.244, and 0.366 L/min) respectively.This study emphasizes the prospect of Fe-Gr electrodes in enhancing the electrocoagulation process of wastewater treatment, which is more economical and environmentally friendly in controlling the contamination of heavy metals.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.070
Threshold uncertainty score0.491

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.219
Teacher spread0.215 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2025
Admission routes1
Has abstractyes

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