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Record W4413042899 · doi:10.1021/acssuschemeng.5c04838

Comparative Analysis of Direct Ammonia and Hydrogen Utilization: A Holistic Sustainability Perspective for Decarbonizing Transport and Power Sectors

2025· article· en· W4413042899 on OpenAlexaff
Malik Sajawal Akhtar, Munawwar Ali Khan, Vahid Khaligh, Jay Liu

Bibliographic record

VenueACS Sustainable Chemistry & Engineering · 2025
Typearticle
Languageen
FieldChemical Engineering
TopicAmmonia Synthesis and Nitrogen Reduction
Canadian institutionsTrinity Western University
FundersMinistry of Science and ICT, South Korea
KeywordsSustainabilityPerspective (graphical)AmmoniaPower (physics)BusinessEnvironmental economicsNatural resource economicsChemistryEconomicsComputer scienceEcologyThermodynamics

Abstract

fetched live from OpenAlex

Green hydrogen is pivotal for decarbonizing the transport and power sectors, but it faces significant challenges related to long-term storage and distribution. Green ammonia, a promising hydrogen carrier, offers logistical advantages; however, its end-use viability remains largely unexamined. This study compares two pathways: (1) hydrogen produced from ammonia cracking, used at refueling stations for hydrogen fuel cell vehicles and in stationary power plants; and (2) direct use of ammonia at fueling stations for direct ammonia fuel cell (DAFC) vehicles and in DAFC-based power plants. A techno-economic analysis was conducted to evaluate the levelized cost of fuel (LCOF), levelized cost of electricity (LCOE), and carbon abatement cost (CAC) for all scenarios. Results indicate that for transport hydrogen (Case 1) achieves an LCOF of 0.078 $/km, outperforming ammonia at 0.133 $/km, owing to its higher energy density. For power generation, hydrogen’s LCOE (0.49 $/kWh) is lower than ammonia (0.93 $/kWh), though both remain above the conventional pathway owing to lower fuel cell efficiencies and higher capital costs. The CAC analysis indicates that decarbonizing the transport sector is more economical with hydrogen (353 $/tCO 2 ) or ammonia (595 $/tCO 2 ) compared to the power sector, where CAC rises to 1525 $/tCO 2 for hydrogen and 4510 $/tCO 2 for ammonia. Forecast analysis suggests that by 2030, both hydrogen and ammonia with LCOF of 0.064 and 0.055 $/km, respectively, can outperform conventional gasoline (0.07 $/km), with ammonia becoming the most cost-effective option for transportation. This study highlights that hydrogen and ammonia, each offering distinct advantages depending on end-use application and time frame, are mutually enabling solutions for decarbonized energy systems. These findings support the need for policy mechanisms such as carbon tax and targeted technological innovation to bridge cost gaps and address barriers in the energy transition.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.244
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.267
Teacher spread0.254 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations5
Published2025
Admission routes1
Has abstractyes

Explore more

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