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Record W4413270790 · doi:10.1016/j.actbio.2025.08.025

Enamel-like stiffness achieved by poorly oriented nanocrystals in the capping tissue of Mexican beaded lizard osteoderms

2025· article· en· W4413270790 on OpenAlexaff
Adrián Rodríguez-Palomo, Maja Jacobsen, Thorbjørn Erik Køppen Christensen, Mads R. V. Jørgensen, I. Kantor, Gabriella Willan, Anthony Herrel, Arsalan Marghoub, Mehran Moazen, Susan E. Evans, Matthew K. Vickaryous, Catherine J. Williams, Henrik Birkedal

Bibliographic record

VenueActa Biomaterialia · 2025
Typearticle
Languageen
FieldChemistry
Topicthermodynamics and calorimetric analyses
Canadian institutionsUniversity of Guelph
FundersForsknings- og InnovationsstyrelsenNovo Nordisk FondenSvenska Forskningsrådet FormasVINNOVADanish Agency for Science and Higher EducationNordForskNordisk MinisterrådCarlsbergfondetAarhus UniversitetVetenskapsrådetHuman Frontier Science Program
KeywordsMaterials scienceStiffnessLizardNanocrystalEnamel paintComposite materialBiomedical engineeringNanotechnologyMedicineGeologyPaleontology

Abstract

fetched live from OpenAlex

Osteoderms, skeletal structures in the skin, are found in many animals and serve diverse roles. In some lizards, the bony osteoderm has a capping tissue (CT) whose composition and structure remain unknown. Here, the composition and nanostructure of osteoderms from the Mexican beaded lizard (Heloderma horridum) are investigated. The CT is highly mineralized with an extraordinarily high elastic modulus. Within the osteoderm, a transition zone between capping and bone tissue forms a graded increase in mineralization towards the superficial CT. Unlike other examples of mineralized tissues, the CT demonstrates a new combination of physical properties and nanostructural organization. It displays stiffness and hardness similar to enamel, and hydroxyapatite crystals that are an order of magnitude larger than those within the bone tissue and are, thus, reminiscent of enamel crystals. However, in stark contrast to enamel, the CT displays only minimal preferred orientation of the crystallites. Thus, it achieves very high mechanical properties with enamel-like crystal sizes but with near-isotropic microstructural orientation. The Mexican beaded lizard CT presents a highly unusual structural design resulting in high-performance mechanics. STATEMENT OF SIGNIFICANCE: The stiffest tissue in vertebrates is enamel, which is characterized by large, highly oriented nanocrystals. The less stiff bone has smaller nanocrystals and a lower, but still high degree of texture. The osteoderms of the Mexican beaded lizard are herein investigated by a combination of mechanical testing, spatially resolved X-ray diffraction and fluorescence, and 3D X-ray imaging. Surprisingly, the osteoderms have a capping tissue with enamel-like stiffness, significantly larger crystals than the underlying bone but are much less textured. This provides a new type of design for hard biological tissues.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.019
Threshold uncertainty score0.740

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.255
Teacher spread0.247 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations5
Published2025
Admission routes1
Has abstractyes

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