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Record W4413477641 · doi:10.1021/acsnano.5c04077

Molecular Biomimicry and the Synthetic Synapse: Engineering a Stable Synaptogenic Extracellular Matrix

2025· article· en· W4413477641 on OpenAlexafffund
Laila Al‐Alwan, Jean‐Pierre Clément, Teddy A. J. Fisher, Daniel Braatz, Daryan Chitsaz, Ehsan Mohammadifar, Cathleen Hudziak, Markus Hellmund, Janine Mauzeroll, Rainer Haag, Timothy E. Kennedy

Bibliographic record

VenueACS Nano · 2025
Typearticle
Languageen
FieldNeuroscience
TopicNeuroscience and Neural Engineering
Canadian institutionsMcGill UniversityMontreal Neurological Institute and Hospital
FundersNatural Sciences and Engineering Research Council of CanadaCanadian Institutes of Health ResearchMolson FoundationKillam TrustsDeutsche ForschungsgemeinschaftFonds de Recherche du Québec - SantéMultiple Sclerosis Society of Canada
KeywordsBiomimeticsExtracellular matrixNanotechnologyMaterials scienceMatrix (chemical analysis)Cognitive scienceChemical engineeringEngineeringPsychologyComposite materialBiologyCell biology

Abstract

fetched live from OpenAlex

Synapses are highly specialized sites of asymmetric cell-cell contact that mediate information transfer between neurons. Many proteins have been identified that contribute to the complex processes that underlie the formation, organization, and maintenance of synapses, and the molecular biology of synapse formation is increasingly well understood. Surprisingly, synaptic differentiation does not require a cellular target. Hemisynaptic specializations form quickly at sites of neurite adhesion to microspheres coated with a synaptogenic protein or a synthetic cationic polypeptide like polylysine. This raises the possibility that functional hemisynaptic connections could be directed to form onto engineered surfaces; however, studies examining the stability of synaptic specializations formed in the brain onto polylysine-coated beads found that they were unstable and degraded within a few weeks after implantation. Here, we demonstrate that microbeads coated with dendritic polyglycerol amine (dPGA), a nonprotein macromolecular biomimetic of polylysine, promote enhanced synaptogenesis and synapse stability compared to conventional polylysine. We show that a dPGA coating is stable in long-term cell culture, resisting proteolysis, and that dPGA-coated beads cluster neurexin, which is sufficient to direct presynaptic terminal formation. We propose that synthetic synaptogenic extracellular matrices that resist proteolysis could be used to engineer electrodes with enhanced neural biocompatibility and support long-term bidirectional communication with neurons by directing the formation of stable synaptic specializations.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.044
Threshold uncertainty score0.571

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.226
Teacher spread0.218 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2025
Admission routes2
Has abstractyes

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