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Determination of the thermo-electronic and structural properties of polycrystalline metals and single-crystal semiconductors

2025· article· en· W4414043834 on OpenAlexaff
Porfirio E. Martinez-Muñoz, Hector Garcia-Vazquez, Cristian Felipe Ramirez-Gutierrez, Mario E. Rodríguez‐García

Bibliographic record

VenueMeasurement · 2025
Typearticle
Languageen
FieldEngineering
TopicThermodynamic and Structural Properties of Metals and Alloys
Canadian institutionsMcMaster University
FundersConsejo Nacional de Ciencia y Tecnología
KeywordsVan der Pauw methodCrystalliteThermal diffusivitySemiconductorThermal conductivityThermal conductivity measurementElectrical resistivity and conductivityThermal conduction

Abstract

fetched live from OpenAlex

• Correlation established between thermal, electrical, and structural properties. • FDPA, TRM, and Van der Pauw applied to characterize thermo-electronic properties. • Analysis includes polycrystalline metals and semiconductors with varying structures. • Thermal conductivity strongly depends on crystallite size. This study explores the correlation between thermal, electrical, and structural properties of metals, alloys, and single-crystal semiconductors using photothermal techniques, electrical methods, and X-ray diffraction. Polycrystalline metals (Al, Pt, Ti, Cu, AISI 1030 steel, α-brass) and semiconductors (Si, GaSb-Te) were systematically analyzed. Thermal diffusivity was measured using Frequency Domain Photoacoustic (FDPA), and thermal conductivity and volumetric heat capacity using the Thermal Relaxation Method (TRM). A thermal diffusivity image for a Si sample was taken to show the influence of mechanical damage on the thermal transport properties. The structural properties were determined using X-ray diffraction, while the electrical properties were evaluated using the Van der Pauw method. The results show a strong correlation between the thermal, electrical, and structural properties of the materials, specifically with respect to crystallite size and space group. The thermal conductivity is influenced by the crystallite size, while electrical conductivity varies due to extrinsic factors, especially for polycrystalline metals. These results suggest that the Wiedemann-Franz theory needs to be re-evaluated by considering both intrinsic and extrinsic influences on material behavior.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.026
Threshold uncertainty score0.248

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.184
Teacher spread0.166 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes1
Has abstractyes

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