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Record W4414283567 · doi:10.26434/chemrxiv-2025-653md

Connecting the concepts of quantum state tomography and molecular representations for machine learning

2025· preprint· en· W4414283567 on OpenAlexafffund
Raul Ortega-Ochoa, L. Calderón, Mohsen Bagherimehrab, Abdulrahman Aldossary, Tejs Vegge, Tonio Buonassisi, Alán Aspuru‐Guzik

Bibliographic record

VenueChemRxiv · 2025
Typepreprint
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicSpectroscopy Techniques in Biomedical and Chemical Research
Canadian institutionsVector InstituteUniversity of Toronto
FundersNatural Sciences and Engineering Research Council of CanadaNovo Nordisk FondenKing Abdullah University of Science and TechnologyCanada First Research Excellence FundDanmarks GrundforskningsfondDanmarks Tekniske UniversitetNovo NordiskCanadian Institute for Advanced ResearchUniversity of TorontoNatural Resources CanadaMassachusetts Institute of Technology
KeywordsRepresentation (politics)Property (philosophy)Set (abstract data type)Quantum stateQuantumState (computer science)Feature learningDeep learningQuantum machine learning

Abstract

fetched live from OpenAlex

Quantum state tomography has been widely used to reconstruct the quantum state of a system from a set of informationally-complete measurements. Obtaining enough information about, e.g., the wavefunction of a molecule allows its complete characterization. On the other hand, deep learning models for molecular property prediction have demonstrated the capability to predict properties of unseen molecules, thereby internally characterizing them in a latent space spanning potential virtual molecules. In this work, we argue that deep learning can achieve its characterization power by learning an internal representation that is informationally-equivalent to the molecule's density matrix. We call such a representation a deep tomography, akin to quantum state tomography. We discuss how it is possible for property prediction foundation models, trained on data of informationally-complete observables, to have representations that contain the same information as that of a molecule's reduced quantum density matrix. Thus, such learned representation should be sufficient to predict arbitrary properties of arbitrary unseen molecules.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.003
metaresearch head score (Gemma)0.012
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: none
GenreCandidate signal: Methods · Consensus signal: Methods
Teacher disagreement score0.004
Threshold uncertainty score0.017

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0030.012
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0020.002
Science and technology studies0.0010.007
Scholarly communication0.0030.009
Open science0.0020.004
Research integrity0.0030.007
Insufficient payload (model declined to judge)0.0040.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.366
Teacher spread0.351 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreMethods

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes2
Has abstractyes

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