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Record W4414396917 · doi:10.1016/j.jhazmat.2025.139923

Mapping global exposure to POPs in human milk through multivariate fingerprinting

2025· article· en· W4414396917 on OpenAlexaff
Mike Dereviankin, Courtney D. Sandau, Heidelore Fiedler

Bibliographic record

VenueJournal of Hazardous Materials · 2025
Typearticle
Languageen
FieldEnvironmental Science
TopicHealth, Environment, Cognitive Aging
Canadian institutionsMount Royal UniversityUniversity of Calgary
Fundersnot available
KeywordsPrincipal component analysisUnivariateMultivariate statisticsDimensionality reductionMultivariate analysisProjection (relational algebra)Hierarchical clusteringFingerprint (computing)

Abstract

fetched live from OpenAlex

Many persistent organic pollutants (POPs) in human milk present environmental and health concerns, particularly for vulnerable populations such as breastfed infants. This study applied a data exploration dimensionality reduction workflow using Uniform Manifold Approximation and Projection (UMAP) for POP measurements in human milk. This approach focuses on identifying and comparing the compositional patterns-or 'fingerprints'-of POPs rather than just measuring their concentrations. The UMAP approach revealed detailed variations in POP fingerprints that were not detectable with traditional univariate approaches. UMAP approach also improves upon other multivariate approaches, such as hierarchical cluster analysis (HCA) and principal component analysis (PCA). Unlike previous studies focusing solely on concentration differences, UMAP identified distinct regional and economic POP fingerprints. Lower-income countries showed POP fingerprints dominated by DDT-related compounds, while higher-income regions showed distinct fingerprints with greater contributions from PCBs and other legacy pollutants. Temporal analysis captured shifts in POP fingerprints after 2001, corresponding with the expansion from initial focus on PCDD, PCDF, and PCB to the broader group of the original 12 POPs listed under the Stockholm Convention. These results demonstrate how dimensionality reduction techniques, particularly UMAP, can distinguish compositional POP fingerprints across geospatial, temporal, and economic factors, providing a comparative framework for understanding global exposure patterns.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.812
Threshold uncertainty score0.996

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.300
Teacher spread0.284 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2025
Admission routes1
Has abstractyes

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