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Record W4414525779 · doi:10.1002/cjce.70106

Seed crystal/ <scp>MgCl</scp> <sub>2</sub> ‐assisting synthesis hierarchical zeolite <scp>ZSM</scp> ‐5 in the absence of organic templates

2025· article· en· W4414525779 on OpenAlexvenueno aff
Hongtao Liu, Zhaojun Liu, Guonian Yang, Jun Gao, Jiujiang Wang, Gen Li, Hongjuan Zhao, Honghai Liu

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2025
Typearticle
Languageen
FieldChemistry
TopicZeolite Catalysis and Synthesis
Canadian institutionsnot available
Fundersnot available
KeywordsZeoliteMesoporous materialCatalysisFluid catalytic crackingTemplateBET theorySpecific surface area

Abstract

fetched live from OpenAlex

Abstract Hierarchical zeolite ZSM‐5 has attracted enormous attention due to its shape selectivity in catalytic process. However, sustainably obtaining zeolite ZSM‐5 in a completely inorganic synthesis system is still a great challenge. In this study, a facile and inorganic strategy to manipulate the mesopore structure was reported. Taking advantage of grafted Mg species as the source of defect sites, the resultant ZSM‐5 was demonstrated to have a total BET surface area of 363.6 m 2 · g −1 , and a mesoporous surface area of 156.2 m 2 · g −1 . Moreover, the hierarchical material showed much enhanced catalytic cracking activity for heavy oil due to its micro‐mesoporosity structure. This strategy opens a novel way for the green obtaining of zeolites with hierarchical structure.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.009
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMetaresearch
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.008
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.009
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.185
Teacher spread0.179 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes1
Has abstractyes

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