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Record W4414667151 · doi:10.1093/etojnl/vgaf244

Applying eco-indicator sensitivity distribution to evaluate chlorpyrifos risk in grassland soils with prescribed fire and grazing history

2025· article· en· W4414667151 on OpenAlexafffund
Hamzat O. Fajana, Adedamola A. Adedokun, Philip A. Abiolu, Olukayode Jegede, Eric G. Lamb, Steven D. Siciliano

Bibliographic record

VenueEnvironmental Toxicology and Chemistry · 2025
Typearticle
Languageen
FieldEnvironmental Science
TopicPesticide and Herbicide Environmental Studies
Canadian institutionsUniversity of Saskatchewan
FundersNatural Sciences and Engineering Research Council of CanadaUniversity of Saskatchewan
KeywordsGrazingChlorpyrifosSoil waterSoil qualityEcosystemGrasslandSoil testSoil carbon

Abstract

fetched live from OpenAlex

Prescribed fire and grazing can enhance soil ecosystem functions in grasslands but may also induce ecological stress on soil function, making soil more vulnerable to chemical stressors like pesticides, which contaminate grasslands via aerial spray drift. Therefore, this study investigated the effects of prescribed fire-grazing history and chlorpyrifos toxicity on selected soil quality parameters and ecological indicators (eco-indicators) in a fescue prairie grassland soil. Burnt soil from an area subjected to prescribed fire in 2017 and annual cattle grazing and unburnt reference soil from adjacent areas subjected to grazing alone were collected in 2021 and exposed to varying doses of chlorpyrifos. Results showed no interactive effect of fire-grazing and chlorpyrifos toxicity on the measured soil quality parameters and eco-indicators. Whereas the fire-grazing effect in the burnt soil significantly enhanced soil quality parameters like base cations and available nitrogen, it exacerbated chlorpyrifos toxicity on key soil eco-indicators like oribatid mites and soil extracellular enzyme, acid phosphatase. Based on the eco-indicator sensitivity distribution framework, the burnt soil with history of fire and grazing was generally susceptible to chlorpyrifos, with ecological hazard concentrations at 5% (HC5Eco) to 50% (HC50Eco) ranging from 0.08 to 1.5 mg/kg compared with 0.5 to 4.0 mg/kg in the unburnt soil with grazing history alone. Regardless of the fire treatment, arylamidase, an enzyme crucial for nitrogen mineralization, was the most sensitive soil eco-indicator to chlorpyrifos toxicity. These findings suggest that fire, in combination with grazing, may increase the susceptibility of soil eco-indicators to chlorpyrifos toxicity, potentially due to changes in organic matter quality or increased stress from pyric byproducts.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.006
Threshold uncertainty score0.012

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0010.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.202
Teacher spread0.197 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes2
Has abstractyes

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