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Record W4414679049 · doi:10.1002/cphc.202500569

Corrigendum: Protonation Effects on the Benzoxazine Formation Pathways and Products Distribution

2025· article· en· W4414679049 on OpenAlexaboutno aff

Bibliographic record

VenueChemPhysChem · 2025
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicPhenothiazines and Benzothiazines Synthesis and Activities
Canadian institutionsnot available
Fundersnot available
KeywordsProtonationDistribution (mathematics)Product distributionReaction mechanism

Abstract

fetched live from OpenAlex

Francisco W. M. Ribeiro1,2; Isaac Omari;1 J. Scott McIndoe1* Thiago Carita Correra2,* 1Department of Chemistry, University of Victoria, P. O. Box 3065, Victoria, BC V8W 3V6, Canada 2Department of Fundamental Chemistry, Institute of Chemistry, University of São Paulo Av. Prof. Lineu Prestes, 748, Cidade Universitária, Saão Paulo, Saão Paulo 05508-000, Brazil. Figure 3 in the original manuscript (see Figure 1 in this corrigendum) should be replaced by the corrected version shown in Figure 2 below, where the putative reaction mechanism for the formation of IIc is correctly depicted. In “Side Products Observed in the Presence of Acidic Media” section, page 4, the sentence “IIc could react with another formaldehyde molecule generating the intermediate E after dehydration (Figure 3b)” should be corrected to “The neutral form of IIc ([IIc-H]) could react with another protonated formaldehyde molecule generating the intermediate E after dehydration (Figure 3b)”.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.010
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: Not applicable
GenreCandidate signal: Other · Consensus signal: none
Teacher disagreement score0.107
Threshold uncertainty score0.358

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.010
Meta-epidemiology (narrow)0.0020.001
Meta-epidemiology (broad)0.0020.002
Bibliometrics0.0020.002
Science and technology studies0.0020.001
Scholarly communication0.0030.002
Open science0.0020.001
Research integrity0.0030.003
Insufficient payload (model declined to judge)0.1070.050

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.014
GPT teacher head0.218
Teacher spread0.204 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes1
Has abstractyes

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