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Record W4414813527 · doi:10.1021/acs.analchem.5c04495

Synergistic Inhibition of Nonspecific Binding for Accurate Detection of <i>Escherichia coli</i> O157:H7 and Multilevel Signal Discrimination

2025· article· en· W4414813527 on OpenAlexaff
Yang Zhang, Feng Hu, Kaiyi Zheng, Haoran Li, Tianxi Yang, Chuping Zhao, Roujia Zhang, Xiaodong Zhai, Junjun Zhang, Ruiyun Zhou, Xiaowei Huang, Zhihua Li, Jiyong Shi, Zhiming Guo, Shipeng Gao, Xiaobo Zou

Bibliographic record

VenueAnalytical Chemistry · 2025
Typearticle
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicEscherichia coli research studies
Canadian institutionsUniversity of British Columbia
FundersNatural Science Foundation of Jiangsu Province
KeywordsBiosensorSIGNAL (programming language)Detection limitInterference (communication)Detection theoryAnalytePredictive valueLimit (mathematics)

Abstract

fetched live from OpenAlex

Pathogenic Escherichia coli ( E. coli ), particularly E. coli O157:H7, is a major foodborne pathogen with significant clinical relevance, necessitating accurate and rapid subtype identification. However, the high genetic variability and biological similarity among E. coli strains pose challenges for conventional signal-strain detection methods, often resulting in false-positive outcomes. In this study, we developed a novel biosensing strategy based on plasmonic nanostructures functionalized with heterogeneous recognition elements that target two distinct epitopes of E. coli O157:H7. The sensor incorporates biological silent Raman tags for ratiometric signal output and magnetic enrichment to improve selectivity and minimize interference from nontarget bacteria. This design ensures excellent reproducibility and operational stability. The biosensor demonstrated an impressive limit of detection (LOD) of 1.2 CFU/mL, outperforming most existing methods. Furthermore, a cutoff value of 0.32 for the signal ratio yielded a positive predictive value of 98% and a negative predictive value of 94%, demonstrating a clear signal boundary and high accuracy for various types of signals. These results highlight the potential of our plasmonic biosensor as a rapid, ultrasensitive, and reliable point-of-care diagnostic tool for pathogen detection in complex food matrices.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.004

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.001
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.019
GPT teacher head0.298
Teacher spread0.279 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes1
Has abstractyes

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