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Record W4415075911 · doi:10.1002/pol.20250655

Polyamide/ <scp> SiO <sub>2</sub> </scp> /Gelatin In Situ Composite From <scp>BIC</scp> /Sol–Gel Co‐Reaction for Dual Applications in Hg <sup>2+</sup> Electrochemical Probing and Both Anionic/Cationic Dyes Removal

2025· article· en· W4415075911 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueJournal of Polymer Science · 2025
Typearticle
Languageen
FieldMaterials Science
TopicCorrosion Behavior and Inhibition
Canadian institutionsMinistry of Agriculture
FundersNational Natural Science Foundation of China
KeywordsElectrochemistryAdsorptionPolyamideCationic polymerizationIn situSubstrate (aquarium)ElectrodeDetection limitMethylene blue

Abstract

fetched live from OpenAlex

ABSTRACT In this study, a novel polyamide (PA)/SiO 2 /gelatin (GL) in situ hybrid material (PA‐Si‐GL) was successfully prepared at room temperature by introducing amphoteric biomass, GL, as a reaction substrate into benzoxazine‐isocyanide chemistry (BIC)/sol–gel reaction system. The systematic characterization of PA‐Si‐GL's chemical structure and fundamental properties was implemented subsequently. The in situ integration of GL with diverse N,O‐containing segments (amide, phenol OH, and SiOSi) present in PA/SiO 2 fraction could strengthen the affinity between PA‐Si‐GL and Hg 2+ /dyes. PA‐Si‐GL's binding for Hg 2+ was reasonably utilized to realize the probing of this highly poisonous heavy metal. With PA‐Si‐GL as the active modifier, the modified glassy carbon electrode (GCE) (termed as PA‐Si‐GL/GCE) exhibited a specific enrichment‐enhanced electrochemical response toward Hg 2+ , with a detection limit as low as 2.8 × 10 −10 mol/L. Concurrently, PA‐Si‐GL can remove both anionic (Congo red [CR]) and cationic (methylene blue [MB]) dyes from contaminant water. The maximum adsorption capacities of PA‐Si‐GL for CR/MB reached 680.1/1001.3 mg/g (298 K), respectively. Mechanistic studies regarding Hg 2+ probing and dyes adsorption by PA‐Si‐GL were carried out by the combination of experimental comparison and chemical calculation.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.014
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.262
Teacher spread0.252 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it