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Record W4415226199 · doi:10.1016/j.seppur.2025.135614

High-yield selective extraction of metal iron from JSC-1A using molten salt electrolysis

2025· article· en· W4415226199 on OpenAlexafffund
Navid Assi, Anqi Wang, Connor J. MacRobbie, Jean-Pierre Hickey, John Z. Wen

Bibliographic record

VenueSeparation and Purification Technology · 2025
Typearticle
Languageen
FieldEngineering
TopicExtraction and Separation Processes
Canadian institutionsUniversity of Waterloo
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsCathodeExtraction (chemistry)ElectrolysisMetalRegolithElectrochemistryElectrolytic processIron powderMagnetite

Abstract

fetched live from OpenAlex

Establishing a sustainable long-term human presence on the Moon and other celestial bodies requires the advancement of in-situ resource utilization (ISRU) for both oxygen and metals from the regolith. Among various metals, iron is considered a critical lunar resource due to its potential in construction, infrastructure, and energy systems. However, selective iron extraction from lunar regolith is challenging because of the complex composition of minerals. In this study, an FFC Cambridge process was employed to perform electrolysis of JSC-1 A in molten CaCl 2 at 900 with a variety of voltages between 1.0 and 1.75 V, allowing effective and selective extraction of metallic iron without contamination from the reduction of other metal oxides. During electrolysis, the reduced metallic iron was directly adhered onto the surface of the Nichrome cathode wire, leading to convenient collection and purification of the product. The optimal yield of pure metallic iron extraction and current efficiency from JSC-1 A were approximately 83.47 % and 79.65 %, respectively, achieved at 1.5 V. Comparing the electrochemical reduction behaviors of Fe 2 O 3 and FeO with the regolith matrix provided a better understanding of the different reaction stages during the process, which caused significant changes in the size and morphology of the produced metallic iron crystals. The deposited product on the cathode surface was also found to be affected by the concentration of iron oxide in the mixture. These findings demonstrate the feasibility of selective and efficient in-situ iron extraction from lunar regolith for future space missions through controlled electrochemical reduction. • Selective extraction of metallic iron from lunar regolith simulant (JSC-1A) via the FFC process. • High-purity and high-yield production enabled by reduction of powder-form simulant. • Elimination of additional chemical reducer to allow fully in-situ production of metal. • Identification of complex reduction stages of Fe from JSC-1A. • ISRP-based metallic feedstock production on the Moon supported by experimental finding.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.217
Threshold uncertainty score0.617

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.277
Teacher spread0.267 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2025
Admission routes2
Has abstractyes

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