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Characterisation of off-flavour compounds and their sensory impact on Lupinus angustifolius L.: Special emphasis on volatile markers of green, grassy, and beany aroma notes and bitter taste

2025· article· en· W4415764962 on OpenAlexaff
Piyumi Chathurangi Wanniarachchi, Russell Keast, Simone Lewin, Gregory R. Cawthray, Rewati Raman Bhattarai, Mauro Mocerino, Sarita Jane Bennett, Greg Shea, Ranil Coorey

Bibliographic record

VenueFood Chemistry · 2025
Typearticle
Languageen
FieldAgricultural and Biological Sciences
TopicBotanical Research and Chemistry
Canadian institutionsBentley (Canada)
FundersDepartment of Primary Industries and Regional Development, Government of Western AustraliaNSW Department of Primary IndustriesParkinson’s Western Australia
KeywordsLupinus angustifoliusAromaTasteSensory analysisMass spectrometryGas chromatography–mass spectrometryPartial least squares regressionGas chromatography

Abstract

fetched live from OpenAlex

Volatile organic compounds (VOCs) across five varieties of Lupinus angustifolius L. were quantified using headspace solid-phase microextraction assisted gas chromatography orbitrap mass spectrometry (HS-SPME-GC-Orbitrap-MS), and alkaloids were analysed using liquid chromatography mass spectrometry (LC-MS) with their sensory impact assessed through a trained panel. To our knowledge, this is the first systematic comparison of off-flavour profiles across multiple L. angustifolius varieties grown in Western Australia under different sowing conditions. Two-way analysis of variance (ANOVA) revealed that quinolizidine alkaloids (QAs) and VOCs in L. angustifolius were regulated by interactions between the sowing time and variety. Partial Least Squares regression (PLS-R) indicated that PBA Jurien exhibited stronger bitterness and a 'green/grassy' aroma, whereas Tanjil had a stronger beany aroma. Kalya and Mandelup showed lower contribution to undesirable sensory notes. Pearson correlation analysis revealed a weak positive, statistically significant relationship between 'green/grassy' aroma and specific lipoxygenase (LOX) activity across L. angustifolius varieties, whereas no significant correlation was observed between 'beany' aroma and specific LOX activity. Lupanine showed a strong positive correlation with specific LOX activity and a moderate positive association with bitterness. This study provides insights into screening L. angustifolius varieties with reduced 'beany', 'green/grassy' aromas and bitterness for future human food applications.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.323
Threshold uncertainty score0.306

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.234
Teacher spread0.221 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes1
Has abstractyes

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