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Record W4415772909 · doi:10.1029/2025ea004781

Combined Retrieval of Cloud Parameters for TEMPO Measurements Over Canada Using Oxygen Dimer and B Band Absorption

2025· article· en· W4415772909 on OpenAlexafffundabout
Lukas Fehr, Adam Bourassa, D. A. Degenstein, Daniel Zawada, C. A. McLinden, Debora Griffin, Caroline R. Nowlan, Heesung Chong, HUIQUN WANG

Bibliographic record

VenueEarth and Space Science · 2025
Typearticle
Languageen
FieldEnvironmental Science
TopicAtmospheric aerosols and clouds
Canadian institutionsEnvironment and Climate Change CanadaUniversity of Saskatchewan
FundersEnvironment and Climate Change Canada
KeywordsReflectivityTroposphereAbsorption (acoustics)Air pollutionCloud computingAtmosphere (unit)Air quality index

Abstract

fetched live from OpenAlex

Abstract Tropospheric Emissions: Monitoring of Pollution (TEMPO) provides valuable hourly measurements of airborne pollutants over North America. Data quality over snowy surfaces may degrade due to difficulty in accurately characterizing surface reflectivity and cloud properties, as snow and cloud are both highly reflective and therefore challenging to distinguish optically. Cloud properties for satellite‐based trace gas retrievals are commonly extracted from measurements of oxygen, through either direct absorption (A band, B band) or collisional absorption (oxygen dimer). Here we investigate a combination of the two methods, with potential for extracting additional cloud information over challenging scenes due to the different responses of the two methods to various atmospheric conditions. A combined retrieval is successfully applied to simplified simulated data, extracting cloud information under conditions which would cause either retrieval to fail on its own. A second technique is demonstrated on the simulated data which attempts to flag partially cloudy scenes in the absence of external surface reflectivity information. The individual retrievals are applied to TEMPO data and compared in order to investigate their compatibility for potential use in combined retrievals. Variability in effective cloud fraction is found to be on the order of 0.1, and a bias in optical centroid pressure (representing the altitude of the cloud) is observed between methods, up to 50 hPa for fully overcast scenes and higher for partially cloud scenes. Further investigation is required to determine if these discrepancies are due to retrieval error, instrument calibration, or physical differences between spectral bands.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.507
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.015
GPT teacher head0.234
Teacher spread0.218 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes3
Has abstractyes

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