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Record W4415919278 · doi:10.1021/acsestwater.5c00947

Uncovering Hidden Pollution: Diffuse Contaminant Sources in a Sparsely Industrialized Estuarine System

2025· article· en· W4415919278 on OpenAlex
Imran Shafique, Raees Ahmad, Kyung‐Hoon Shin, Yusang Cho, Neung‐Hwan Oh, Jin Hur, Sunghwan Kim

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueACS ES&T Water · 2025
Typearticle
Languageen
FieldEnvironmental Science
TopicToxic Organic Pollutants Impact
Canadian institutionsIONICS Mass Spectrometry (Canada)
FundersKorea Institute of Marine Science and Technology promotionNational Research Foundation of Korea
KeywordsEstuaryContaminationSedimentPollutantTributaryPollutionAquatic ecosystemEcosystemWater pollution

Abstract

fetched live from OpenAlex

Understanding sediment contamination in low-industrial activity areas remains a critical but understudied issue, particularly in estuarine ecosystems subject to diffuse pollution sources. This study employed nontarget screening with high-resolution mass spectrometry to analyze sediment samples from Ganggu Estuary, South Korea, to evaluate the composition and distribution of sediment contaminants in a region lacking heavy industry but influenced by agriculture, fisheries, and tributary discharges. The investigation revealed that contamination stems from multiple sources, including streams, agricultural runoff, and fish market discharges. A total of 678 chemicals were identified, including human and veterinary drugs (8.7%), food additives (6.5%), pesticides (2.8%), and PFAS (1.9%), with spatial variability confirmed by total organic carbon (TOC) analysis. Notably, this study is the first to report the detection of dinoseb, a banned herbicide in estuarine sediments, identified with high confidence alongside key pollutants such as 6:2 fluorotelomer sulfonic acid and 2,4-di- tert -butylphenol. We linked contamination hotspots to U-shaped river bends, streamwater and sediment inputs, and agricultural runoffs, and highlight the role of natural processes in pollutant deposition in a region where heavy industry is absent, yet diffuse sources still drive significant contamination.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.387
Threshold uncertainty score0.754

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.017
GPT teacher head0.222
Teacher spread0.205 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it