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Record W4416014198 · doi:10.1021/acsnano.5c11922

Local Collagen Fibril Orientation Guides Mineral Growth Direction and Morphology: Parallelism in Bone, Cartilage, Enthesis Fibrocartilage, Calcifying Tendon, and Dentin

2025· article· en· W4416014198 on OpenAlexafffund
Joseph Deering, Daniel J. Buss, Monzur Murshed, Natalie Reznikov, Marc D. McKee

Bibliographic record

VenueACS Nano · 2025
Typearticle
Languageen
FieldMaterials Science
TopicCollagen: Extraction and Characterization
Canadian institutionsShriners Hospitals for Children - CanadaMcGill University
FundersFonds de Recherche du Québec - SantéCanadian Institutes of Health ResearchNatural Sciences and Engineering Research Council of CanadaCanada Research Chairs
KeywordsMineralization (soil science)EnthesisBiomineralizationFibrillogenesisCalcificationType I collagenExtracellular matrixBone mineralMicroscale chemistryApatite

Abstract

fetched live from OpenAlex

Extracellular matrix mineralization is a complex process that starts at the atomic scale and cascades upward. The organic matrix forms first, and then mineralization ensues. Using an array of 2D and 3D X-ray and electron microscopy techniques, we have characterized the relationship between the 3D assembly of collagen fibrils (in terms of bundling and long-range coalignment) and mineral, with a specific focus on how the collagen architecture patterns mineralization in various biological tissues, including bone, cartilage, enthesis fibrocartilage, calcifying tendon and dentin─including ectopic calcification events. In the locally oriented type I collagen-rich matrix of lamellar bone, volumetric simulations of mineral growth resulted in an estimated growth rate of 1.67× along the long axis direction of collagen for prolate mineral aggregates (tesselles). A similar prolate shape was seen for the well-aligned collagen of calcifying fibrocartilage, with the collagen direction and preferred mineral growth direction diverging by ∼15°. In woven bone (ordered and disordered type I collagen), mineral growth is more isotropic, and in calcifying cartilage (disordered type II collagen), mineral foci grow in an equiaxed fashion, producing spherical aggregates of mineral. A stratified/layered structure was also found in the mineral foci of periosteal collar calcifying cartilage. In predentin, planar arrays of type I collagen shape the oblate morphology of calcospherites. Regardless of whether mineralization occurs orthotopically or ectopically, a clear parallelism exists in vivo between the local collagen fibril texture and the preferred direction of microscale mineral growth, expansion, and patterning.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.129
Threshold uncertainty score0.663

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.252
Teacher spread0.243 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2025
Admission routes2
Has abstractyes

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