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Record W4416072389 · doi:10.1021/acs.iecr.5c03080

Experimental Analysis of a Sabatier Reactor for Renewable Natural Gas Generation from Biogas: Ignition, Parameter Sensitivity Analysis, and Stability

2025· article· en· W4416072389 on OpenAlexafffund
Yichen Zhuang, David S. A. Simakov

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2025
Typearticle
Languageen
FieldChemical Engineering
TopicCatalysts for Methane Reforming
Canadian institutionsUniversity of Waterloo
FundersNatural Sciences and Engineering Research Council of CanadaCanada Foundation for Innovation
KeywordsBiogasMethaneRenewable energyNatural gasRefineryMethanationRenewable natural gas

Abstract

fetched live from OpenAlex

Biogas is a product of anaerobic fermentation, which is rich in CO 2 . The upgrade of biogas to renewable natural gas (RNG) is commercially achieved by separating carbon dioxide (CO 2 ) and impurities to improve its quality. As an alternative, the CO 2 contained in biogas can be directly converted into CH 4 via the thermocatalytic Sabatier reaction without separation, using H 2 generated by water electrolysis (utilizing renewable or surplus, low-carbon-footprint electricity). One of the major elements of this technology is the configuration of the Sabatier reactor. For industrial applications, it is beneficial to eliminate the energy-intensive CO 2 separation step, converting biogas to RNG directly. In this study, we report the experimental lab-scale proof of concept of the autothermal Sabatier reactor for direct biogas upgrade. We demonstrate a completely autothermal operation of the air-cooled, stainless steel reactor using a commercial Ni catalyst with a synthetic biogas feed. The effects of feed temperature, space velocity, and reactor cooling were investigated using three prototypes with different sizes and configurations. The maximum CO 2 conversion of 91% with 100% selectivity to CH 4 generation was achieved in a 10″-length reactor, over 100 h of continuous, stable operation, without any external reactor heating or feed preheating.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.002
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.193
Threshold uncertainty score0.964

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.002
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0010.003
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.075
GPT teacher head0.338
Teacher spread0.263 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2025
Admission routes2
Has abstractyes

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