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Record W4416128653 · doi:10.5194/bg-22-6695-2025

Reviews and syntheses: Artisanal and small-scale gold mining (ASGM)-derived mercury contamination in agricultural systems: what we know and need to know

2025· article· en· W4416128653 on OpenAlexafffund
David S. McLagan, Excellent O. Eboigbe, Rachel Strickman

Bibliographic record

VenueBiogeosciences · 2025
Typearticle
Languageen
FieldEnvironmental Science
TopicMercury impact and mitigation studies
Canadian institutionsQueen's UniversityGeological Survey of Canada
FundersIAMGOLDSchool of Graduate Studies, Queen's UniversityQueen's University
KeywordsMercury (programming language)MethylmercuryAgricultureGold miningBioaccumulationBiogeochemical cycleFood chainContamination

Abstract

fetched live from OpenAlex

Abstract. The escalating global demand for gold has fuelled the rapid expansion of artisanal and small-scale gold mining (ASGM), which has become the largest source of mercury (Hg) emissions worldwide. Here we synthesize current research on the pervasive contamination of agricultural systems by ASGM-derived Hg, identifying the key environmental pathways and subsequent risks to food security. Within these systems, Hg undergoes complex biogeochemical transformations, with the methylation of inorganic Hg into its highly neurotoxic form, methylmercury (MeHg), being a critical process. This is particularly pronounced in rice paddy systems, where microbial activity and favourable redox conditions facilitate Hg methylation, resulting in the bioaccumulation of MeHg in rice grains – a staple food for billions. However, this synthesis reveals that atmospheric uptake is important to total Hg loadings in rice, and more so in tissues of crops grown in unsaturated soils. Indeed, we stress the importance of assessing all potential uptake pathways of Hg in agricultural systems: foliar assimilation from air, uptake from soils/water (particularly MeHg in rice), direct deposition to surfaces, and consumption of contaminated crop tissues (by both humans and livestock/poultry), to delineate the source and ratios of the different pools of Hg within crops and their consumers. A common shortcoming in past studies of ASGM-derived Hg in agricultural systems is that they have commonly overlooked one or more of these uptake pathways. These findings underscore a significant threat to global food chains and human health through the consumption of Hg contaminated produce. Mitigating these risks requires an improved understanding of the quantity of emissions/releases from ASGM, input pathways, and Hg biogeochemical cycling and fate in agricultural landscapes, paving the way for targeted interventions and sustainable management strategies to protect vulnerable communities. We suggest that these goals can be achieved through strategic international and interdisciplinary collaborations, novel and accessible technologies, and care for the dissemination of scientific information to impacted communities.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.401
Threshold uncertainty score0.394

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.022
GPT teacher head0.258
Teacher spread0.236 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2025
Admission routes2
Has abstractyes

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