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Record W4416192210 · doi:10.5194/bg-22-6749-2025

Deltaic burial of authigenic calcite modulates the carbon balance of hardwater lakes

2025· article· en· W4416192210 on OpenAlexaff
Benedict Mittelbach, Margot E. White, Timo Rhyner, Negar Haghipour, Marie‐Elodie Perga, Nathalie Dubois, Timothy I. Eglinton

Bibliographic record

VenueBiogeosciences · 2025
Typearticle
Languageen
FieldEarth and Planetary Sciences
TopicMarine and coastal ecosystems
Canadian institutionsUniversity of British Columbia
FundersInstitut National de Recherche pour l'Agriculture, l'Alimentation et l'EnvironnementUniversité de LausanneUniversité de GenèveEidgenössische Technische Hochschule ZürichSchweizerischer Nationalfonds zur Förderung der Wissenschaftlichen ForschungÉcole Polytechnique Fédérale de LausanneUniversité Savoie Mont Blanc
KeywordsCalciteAuthigenicTotal organic carbonCarbon cycleDissolved organic carbonCarbon fibersTotal inorganic carbonRadiocarbon datingSediment

Abstract

fetched live from OpenAlex

Abstract. Inland waters play an important role in the terrestrial carbon cycle by burying carbon in aquatic sediments while simultaneously releasing CO2 to the atmosphere and laterally exporting carbon along the land-ocean aquatic continuum. Especially in hardwater lakes, the close connection between primary production and calcite precipitation results in a poorly understood balance of carbon burial and release, with stronger coupling of organic and inorganic processes than in softwater lakes. To better understand these dynamics, we analyzed organic and inorganic carbon fluxes in a yearlong (June 2022 to June 2023) sediment trap study in Lake Geneva, the largest natural lake in Western Europe. Two sediment traps – one deployed in the subaqueous delta of the upper Rhône River, the other in the lake's deepest basin – were sampled monthly. Analyzing radiocarbon (14C) signatures of particulate organic and inorganic carbon allowed us to resolve allochthonous (external) and autochthonous (internal) contributions to absolute carbon fluxes. We found that the flux of autochthonous particulate inorganic carbon in the river-proximal deltaic site was approximately four times higher than in the distal one. This is likely the result of calcite precipitation driven by increased fluvial supply of nutrients and suspended carbonate-bearing particles. Sediment core analysis in the same location suggests efficient preservation of this calcite over centennial timescales, which we conservatively estimate around 7–10 Gg C yr−1 lake-wide. This indicates at least partial offset of the CO2 released during calcite precipitation and is an important flux to be considered in mechanistic carbon cycle models.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.093
Threshold uncertainty score0.963

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.009
GPT teacher head0.202
Teacher spread0.194 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designObservational
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2025
Admission routes1
Has abstractyes

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