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Record W4416291187 · doi:10.26434/chemrxiv-2025-6c250

A Robust and Versatile Generative Model for Inverse Design of Polymers

2025· article· W4416291187 on OpenAlexaff
Haoke Qiu, Haozhe Huang, Hong-Li Yang, Alán Aspuru‐Guzik, Zhao‐Yan Sun

Bibliographic record

VenueChemRxiv · 2025
Typearticle
Language
FieldMaterials Science
TopicMachine Learning in Materials Science
Canadian institutionsUniversity of Toronto
Fundersnot available
KeywordsHeuristicsInverseGenerator (circuit theory)PolymerGenerative DesignGenerative grammar

Abstract

fetched live from OpenAlex

Efficiently designing polymers to meet specific requirements can expedite their translation into practical applications and lower development costs. Although generative inverse design is more efficient than trial-and-error or forward prediction–screening strategies, the imperfect validity of current polymer generative models prevents their seamless integration into scientific discovery workflows. Moreover, their limited controllability—such as the inability to reliably generate polymers with specific functional groups or classes—further constrains their practical utility. In this work, we integrate the robust Group SELFIES method with the state-of-the-art polymer generator PolyTAO to achieve generating 100% chemically valid polymer structures, removing a longstanding bottleneck in polymer design. Compared with previous polymer generation models, this work can generate—on demand—polymers that match specified chemical motifs, polymer classes, and target properties across an effectively unbounded chemical space. We further introduce a task-agnostic, continuous pretraining strategy that combines physics-informed heuristics with reinforcement learning. This approach preserves strong generative performance on user-defined tasks, even in low-data regimes. As a proof of concept, we rigorously validated the dielectric constants of 30 polyimides generated via controlled, on-demand design using first-principles calculations, finding deviations of less than 10% from their target values. Designed as a powerful backend engine for polymer inverse design, our model is deployment-ready, and integrates seamlessly with high-throughput, self-driving laboratories and industrial synthesis pipelines.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.460
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.051
GPT teacher head0.279
Teacher spread0.229 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes1
Has abstractyes

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