A Cobalt Borate Built by {B <sub>12</sub> } and {Co <sub>3</sub> } Clusters for Photothermal Conversion
Bibliographic record
Abstract
A novel cobalt dodecaborate {Co 3 (H 2 O) 3 } 2 B 12 O 24 ( 1 ) was first made under solvothermal conditions. It is a 3D neutral framework built by the sandwiched {B 12 O 24 }@{Co 3 (H 2 O) 3 } 2 cluster, in which a crown-like B 12 O 24 ({B 12 }) cluster is capped by two Co 3 O 6 (H 2 O) 3 ({Co 3 }) units. The trinuclear {Co 3 } cluster is first found in borates. Due to the aggregation of Co 2+ with a d–d transition, 1 has a broad absorption band from visible to near-infrared (NIR) regions. Photothermal conversion tests reveal that 1 exhibits promising photothermal conversion efficiency (27.3%) under the irradiation of a 1064 nm NIR light, furthermore with excellent cyclic stability. This work represents the first investigation of photothermal conversion performances in crystalline borates, highlighting the potential of borate-based materials for photothermal conversion applications.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".