A Cobalt Borate Built by {B <sub>12</sub> } and {Co <sub>3</sub> } Clusters for Photothermal Conversion
Bibliographic record
Abstract
A novel cobalt dodecaborate {Co 3 (H 2 O) 3 } 2 B 12 O 24 ( 1 ) was first made under solvothermal conditions. It is a 3D neutral framework built by the sandwiched {B 12 O 24 }@{Co 3 (H 2 O) 3 } 2 cluster, in which a crown-like B 12 O 24 ({B 12 }) cluster is capped by two Co 3 O 6 (H 2 O) 3 ({Co 3 }) units. The trinuclear {Co 3 } cluster is first found in borates. Due to the aggregation of Co 2+ with a d–d transition, 1 has a broad absorption band from visible to near-infrared (NIR) regions. Photothermal conversion tests reveal that 1 exhibits promising photothermal conversion efficiency (27.3%) under the irradiation of a 1064 nm NIR light, furthermore with excellent cyclic stability. This work represents the first investigation of photothermal conversion performances in crystalline borates, highlighting the potential of borate-based materials for photothermal conversion applications.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".