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Record W4416674486 · doi:10.1021/acs.est.5c11930

Trade-Offs between Grid Connectivity and Operational Flexibility in Reducing the Cost and Carbon Footprint of Green Ammonia

2025· article· en· W4416674486 on OpenAlexafffund
Stefano Mingolla, Kevin H. R. Rouwenhorst, Paolo Gabrielli, Giovanni Sansavini, Magdalena M. Klemun, Zhongming Lu

Bibliographic record

VenueEnvironmental Science & Technology · 2025
Typearticle
Languageen
FieldChemical Engineering
TopicAmmonia Synthesis and Nitrogen Reduction
Canadian institutionsUniversity of Waterloo
FundersBundesamt für EnergieHong Kong University of Science and TechnologyEidgenössische Technische Hochschule ZürichUniversity of WaterlooResearch Grants Council, University Grants CommitteeUniversity of TwenteNatural Sciences and Engineering Research Council of CanadaJohns Hopkins University
KeywordsGreenhouse gasFlexibility (engineering)Carbon footprintRenewable energyBaseline (sea)Software deploymentCost of electricity by sourceFossil fuelGridProduction (economics)

Abstract

fetched live from OpenAlex

High Resolution Image Download MS PowerPoint Slide Ammonia is essential for fertilizer production and industrial applications, but conventional synthesis is highly carbon-intensive due to reliance on fossil-based hydrogen. Producing “green ammonia” with renewables-based electrolytic hydrogen offers lower emissions and greater resilience to fossil fuel market volatility, though at a higher cost. To reduce infrastructure overbuilding and associated costs, two main strategies have been proposed: (1) grid connection under emission caps and (2) increased operational flexibility. Yet, their relative benefits remain location-specific and uncertain. Here, we evaluate these strategies across a wide range of European Union (EU) weather patterns using the levelized cost of ammonia (LCOA) and life-cycle greenhouse gas emissions as benchmarks. We find that grid-connected plants achieve greater cost reductions but are more sensitive to regulatory uncertainty, particularly emission caps, while operational flexibility achieves larger emission cuts. On average, grid-connected plants lower LCOA by 42% (1569 EUR/t NH 3; range: 999–2772) and emissions by 25% (0.66 t CO 2 e/t; range: 0.39–1.15), while flexible off-grid plants reduce costs by 39% (1593 EUR/t; range: 1168–2573) and emissions by 45% (0.49 t CO 2 e/t; range: 0.31–0.94) compared to baseline off-grid, nonflexible green ammonia systems. Benefits are most pronounced in regions with limited renewable resources, though plants in those regions may face competitiveness challenges, potentially making relocation more attractive. Combining both strategies yields only modest additional benefits, except in wind-rich regions. These findings provide robust guidance for selecting cost- and emission-effective strategies, supporting targeted deployment and sector decarbonization.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.194
Threshold uncertainty score0.514

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.232
Teacher spread0.222 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2025
Admission routes2
Has abstractyes

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