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Record W4416743132 · doi:10.1021/acs.chemmater.5c01841

Scalable Polyol Synthesis of Doped Bi <sub>2</sub> Te <sub>3</sub> with Enhanced Thermoelectric Performance

2025· article· en· W4416743132 on OpenAlexafffund
Madison Donohoe, Ehsan Niknam, Tianze Zou, J. B. Kycia, Holger Kleinke

Bibliographic record

VenueChemistry of Materials · 2025
Typearticle
Languageen
FieldMaterials Science
TopicAdvanced Thermoelectric Materials and Devices
Canadian institutionsUniversity of Waterloo
FundersSocial Sciences and Humanities Research Council of Canada
KeywordsDopantThermoelectric effectDopingCrystalliteThermoelectric materialsWork (physics)

Abstract

fetched live from OpenAlex

Bi 2 Te 3 -based compounds remain one of the most effective thermoelectric materials for low-temperature applications, and their properties can be further enhanced by nanostructuring and dopant incorporation. This work demonstrates significant enhancement of n -type Bi 2 Te 3 synthesized by scalable, solution-based methods through the incorporation of copper, sulfur, and selenium. A peak zT of 1.23 at 383 K and an average zT of 1.11 between 314 and 533 K were achieved. Multiple dopant incorporation strategies were evaluated to identify the most effective approach for achieving uniform dopant distribution, and anisotropy effects arising from preferred crystallite orientation were investigated, demonstrating its influence on transport properties. Overall, this study demonstrates a fast, cost-effective, and scalable synthesis route for Bi 2 Te 3 with enhanced thermoelectric performance, advancing the development of efficient materials for waste heat recovery and sustainable energy technologies.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.006
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.203
Teacher spread0.198 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2025
Admission routes2
Has abstractyes

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