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Record W4416788729 · doi:10.5194/amt-18-7105-2025

Reduction of airmass-dependent biases in TCCON XCH <sub>4</sub> retrievals during polar vortex conditions

2025· article· en· W4416788729 on OpenAlexaff
Jonas Hachmeister, Debra Wunch, Erin McGee, Kimberly Strong, Rigel Kivi, Justus Notholt, Thorsten Warneke, Matthias Buschmann

Bibliographic record

VenueAtmospheric measurement techniques · 2025
Typearticle
Languageen
FieldEnvironmental Science
TopicAtmospheric and Environmental Gas Dynamics
Canadian institutionsUniversity of Toronto
FundersDeutsche ForschungsgemeinschaftAlfred-Wegener-Institut, Helmholtz-Zentrum für Polar- und Meeresforschung
KeywordsTrace gasPolar vortexSatelliteArcticPolarVortexStandard deviationStratosphereAir mass (solar energy)

Abstract

fetched live from OpenAlex

Abstract. Trace gas measurements from the Total Carbon Column Observing Network (TCCON) are important for monitoring the global climate system and for validating satellite measurements. In the Arctic, ground-based data coverage is relatively limited due the inherent challenges of conducting measurements in this region (e.g., remoteness, harsh weather). Additionally, solar absorption measurements require sunlight and are not possible during polar night. TCCON measurements from the Arctic sites are of significant value for the validation of satellite data products in this region, as these measurements can extend the spatiotemporal coverage in the Arctic. In this study, we investigate the TCCON methane (CH4) retrieval under polar vortex conditions. The CH4 profile exhibits a distinct shape inside the vortex, which is related to the descent of stratospheric air inside the vortex. We show that the standard TCCON CH4 prior does not sufficiently reproduce this profile shape, leading to air mass dependencies (AMDs), increased spectral residuals, and less sensitive averaging kernels. These effects can be explained by the imperfect vertical sensitivity, especially to the stratosphere. We further show that changes in the prior can improve the retrieval within the polar vortex. This leads to mean differences between 1 and 2 ppb in XCH4 compared to the standard retrieval, as well as maximum differences up to roughly 17 ppb. This paper highlights the importance of understanding the limitations of retrieval methods to avoid misinterpretation of data. Furthermore, it emphasizes the need to investigate the shape of trace gas profiles inside the polar vortex to improve profile-scaling retrievals (PSRs) in the Arctic, which could include in situ data campaigns focusing on inside-vortex air.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.178
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.013
GPT teacher head0.230
Teacher spread0.217 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2025
Admission routes1
Has abstractyes

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