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Discovery of polyphosphate-interacting human lysine-rich proteins and their functional implications

2025· article· en· W4416812826 on OpenAlexafffund
Zhiyun Yang, Jin Jin, Kirsten Lehotsky, Isabella Vilhena Freire Martins, Ethan Belrose, Nolan Neville, Zongchao Jia

Bibliographic record

VenueInternational Journal of Biological Macromolecules · 2025
Typearticle
Languageen
FieldMedicine
TopicCoagulation, Bradykinin, Polyphosphates, and Angioedema
Canadian institutionsQueen's University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsInteractomeRegulatorMutagenesisGTPase-activating proteinHuman proteinsFunction (biology)Identification (biology)Protein–protein interactionPlasma protein binding

Abstract

fetched live from OpenAlex

Inorganic polyphosphate (polyP), a conserved phosphate polymer, modulates protein function across diverse biological systems, yet its human protein interactome remains poorly defined. While prior studies identified denaturation-resistant polyP modifications on lysine-rich sequences in yeast and bacteria, such targets in human proteins were previously unknown. Here, we performed a systematic screen of 57 lysine-rich human proteins, selected via mass spectrometry and bioinformatics, identifying 41 proteins that exhibit denaturation-resistant polyP modifications. This marks the first identification of lysine-rich motifs as polyP targets in human proteins. Through mutagenesis and binding assays, we establish these lysine-rich motifs, rather than traditional PASK domains, are critical for polyP binding, with consecutive lysine residues and intrinsic disorder as key determinants. Functional assays demonstrate that polyP binding inhibits phase separation of the transcriptional regulator NKAP, suppresses K-RAS GTPase activation, and reduces DDX55 helicase activity, revealing direct regulatory mechanisms. This work not only marks the first identification of denaturation-resistant polyP modifications in human proteins but also provides a comprehensive resource for investigating polyP's roles in human cellular homeostasis and disease.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.002

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.028
GPT teacher head0.311
Teacher spread0.284 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2025
Admission routes2
Has abstractyes

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Same venueInternational Journal of Biological MacromoleculesSame topicCoagulation, Bradykinin, Polyphosphates, and AngioedemaFrench-language works237,207