Optical Switching of <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow> <mml:msup> <mml:mrow> <mml:mi>χ</mml:mi> </mml:mrow> <mml:mrow> <mml:mo stretchy="false">(</mml:mo> <mml:mn>2</mml:mn> <mml:mo stretchy="false">)</mml:mo> </mml:mrow> </mml:msup> </mml:mrow> </mml:math> in Diamond Photonics
Bibliographic record
Abstract
Diamond's unique physical properties make it a versatile material for a wide range of nonlinear and quantum photonic technologies. However, unlocking diamond's full potential as a nonlinear photonic material with nonzero second-order susceptibility, χ^{(2)}≠0, requires symmetry breaking. In this Letter, we use a nanoscale cavity to demonstrate second-harmonic generation (SHG) in diamond, and demonstrate, for the first time, that the magnitude of diamond's effective χ^{(2)} strongly depends on the electronic configuration of defects in the diamond crystal, such as nitrogen-vacancy centers. The modification of χ^{(2)} arises from photoionization from the negative to neutral charge state, and is manifested by quenching of SHG upon green illumination. Toggling the green illumination allows for optical switching of the device's χ^{(2)}. Optical control of χ^{(2)} by defect engineering opens the door for second-order nonlinear processes in diamond.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.004 | 0.003 |
| Meta-epidemiology (narrow) | 0.002 | 0.002 |
| Meta-epidemiology (broad) | 0.001 | 0.003 |
| Bibliometrics | 0.001 | 0.002 |
| Science and technology studies | 0.001 | 0.002 |
| Scholarly communication | 0.002 | 0.002 |
| Open science | 0.004 | 0.003 |
| Research integrity | 0.002 | 0.003 |
| Insufficient payload (model declined to judge) | 0.061 | 0.002 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; both teacher heads agree on what is shown here.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".