Taming of Low‐Valent Arsenic Compounds and Transfer of Nascent As <sub>2</sub> Facilitated by a Frustrated Lewis Pair
Bibliographic record
Abstract
Abstract The first examples of frustrated Lewis pair (FLP)‐stabilized compounds with formal oxidation states of arsenic ranging from −1 to +1 have been synthesized. These chelates include the metalated arsinidenyl As(─I) anion in FLP{As─K} ( 1 ), which provides access to the parent FLP‐stabilized arsinidene, As(+I)─H, in FLP{As─H} ( 3 ), and a diatomic arsenic(0) allotrope within FLP{As─As}FLP ( 5 ). Irradiation of the As 2 complex 5 represents an unprecedented method for the generation of nascent diarsenic, As 2 nasc , which shows triple‐bond like reactivity with a diene and selective As 2 unit insertion into metal‐metal bonds under mild conditions.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.002 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".